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Mannich-type reaction of (1-methoxy-2-methylpropenyloxy)trimethylsilane with arylaldehydes and aromatic amines catalyzed by perfluorinated rare earth metal salts in fluorous phase perfluorinated alkali metal
其他题名全氟磺酸稀土盐催化的在氟碳相中的Mannich-type反应
Shi M(施敏); Cui SC(崔世聪); Liu YH(刘英豪)
2005
发表期刊Tetrahedron
ISSN0040-4020
卷号61期号:21页码:4965-4970
摘要In this paper, we describe a useful Mannich-type reaction in fluorous phase. By use of perfluorodecalin (C,()F,8, cis- and trans-mixture) as a fluorous solvent and perfluorinated rare earth metal salts such as Sc(OSO2C8F17)(3) or Yb(OSO2C8F17)(3) (2.0 mol%) as a catalyst, the Mannich-type reaction of arylaldehydes with aromatic amines and (1-methoxy-2-methylpropenyloxy)trimethylsilane can be performed for many times without reloading the catalyst and the fluorous solvent. (c) 2005 Elsevier Ltd. All rights reserved.
学科领域金属有机化学
部门归属中科院上海有机所金属有机化学国家重点实验室
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收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/9992
专题金属有机化学国家重点实验室
推荐引用方式
GB/T 7714
Shi M,Cui SC,Liu YH. Mannich-type reaction of (1-methoxy-2-methylpropenyloxy)trimethylsilane with arylaldehydes and aromatic amines catalyzed by perfluorinated rare earth metal salts in fluorous phase perfluorinated alkali metal[J]. Tetrahedron,2005,61(21):4965-4970.
APA 施敏,崔世聪,&刘英豪.(2005).Mannich-type reaction of (1-methoxy-2-methylpropenyloxy)trimethylsilane with arylaldehydes and aromatic amines catalyzed by perfluorinated rare earth metal salts in fluorous phase perfluorinated alkali metal.Tetrahedron,61(21),4965-4970.
MLA 施敏,et al."Mannich-type reaction of (1-methoxy-2-methylpropenyloxy)trimethylsilane with arylaldehydes and aromatic amines catalyzed by perfluorinated rare earth metal salts in fluorous phase perfluorinated alkali metal".Tetrahedron 61.21(2005):4965-4970.
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