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学科主题: 金属有机化学
题名: Mannich-type reaction of (1-methoxy-2-methylpropenyloxy)trimethylsilane with arylaldehydes and aromatic amines catalyzed by perfluorinated rare earth metal salts in fluorous phase perfluorinated alkali metal
其他题名: 全氟磺酸稀土盐催化的在氟碳相中的Mannich-type反应
作者: Shi M(施敏) ; Cui SC(崔世聪) ; Liu YH(刘英豪)
刊名: Tetrahedron
发表日期: 2005-01-01
卷: 61, 期:21, 页:4965-4970
收录类别: SCI
部门归属: 中科院上海有机所金属有机化学国家重点实验室
英文摘要: In this paper, we describe a useful Mannich-type reaction in fluorous phase. By use of perfluorodecalin (C,()F,8, cis- and trans-mixture) as a fluorous solvent and perfluorinated rare earth metal salts such as Sc(OSO2C8F17)(3) or Yb(OSO2C8F17)(3) (2.0 mol%) as a catalyst, the Mannich-type reaction of arylaldehydes with aromatic amines and (1-methoxy-2-methylpropenyloxy)trimethylsilane can be performed for many times without reloading the catalyst and the fluorous solvent. (c) 2005 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9992
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shi M,Cui SC,Liu YH. Mannich-type reaction of (1-methoxy-2-methylpropenyloxy)trimethylsilane with arylaldehydes and aromatic amines catalyzed by perfluorinated rare earth metal salts in fluorous phase perfluorinated alkali metal[J]. Tetrahedron,2005,61(21):4965-4970.
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