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学科主题: 金属有机化学
题名: Bronsted acid-mediated ring-opening reactions of methylenecyclopropanes: a dramatic counter ion effect.
其他题名: 布郎斯特酸催化的亚甲基环丙烷开环反应研究
作者: Shao LX(邵黎雄) ; Huang JW(黄金文) ; Shi M(施敏)
通讯作者: 施敏
刊名: Tetrahedron
发表日期: 2004
卷: 60, 期:51, 页:11895-11901
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学国家重点实验室
英文摘要: We report herein two different ring-opening patterns of methylenecyclopropanes (MCPs) in the presence of two Bronsted acids heptadecafluorooctane-1-sulfonic acid (C8F17SO3H) and toluene p-sulfonic acid (TsOH) under mild conditions: (a) the ring-opening of MCPs by H2O and subsequent etherification give the corresponding homoallylic ethers in the presence of heptadecafluorooctane-1-sulfonic acid; (b) the direct ring-opening of MCPs by the Bronsted acid gives the corresponding homoallylic alcohol derivatives in the presence of toluene p-sulfonic acid. (C) 2004 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9948
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shao LX,Huang JW,Shi M. Bronsted acid-mediated ring-opening reactions of methylenecyclopropanes: a dramatic counter ion effect.[J]. Tetrahedron,2004,60(51):11895-11901.
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