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学科主题: 金属有机化学
题名: Palladium-catalyzed asymmetric allylic substitutions by axially chiral P,S-, S,S-, and S,O-heterodonor ligands with a binaphthalene framework
其他题名: Palladium-Catalyzed Asymmetric Allylic Substitutions by Axially Chiral P,S-; S,S-; and S,O-Heterodonor Ligands with Binaphthalene Framework.
作者: Shi M(施敏) ; Zhang W(张雯)
通讯作者: 施敏
刊名: Tetrahedron-Asymmetry
发表日期: 2004
卷: 15, 期:19, 页:3161-3169
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学国家重点实验室
英文摘要: Axially chiral P,S-heterodonor ligand L1 is effective in the asymmetric allylic substitution of 1,3-diphenylpropenyl acetate with dimethyl malonate. its bidentate coordination pattern to a I'd metal center with both P and S atoms has been unambiguously established by X-ray diffraction and NMR spectroscopic analyses. Herein, we further disclose that axially chiral S,S-heterodonor ligands L2-L4 are also effective in the same reaction to give the allylic alkylation product in moderate to good ee. However, the corresponding S,O-heterodonor ligands are not as effective as the corresponding P,S- or S,S-heterodonor ligands in the same asymmetric reaction. (C) 2004 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000224447500020
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9940
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shi M,Zhang W. Palladium-catalyzed asymmetric allylic substitutions by axially chiral P,S-, S,S-, and S,O-heterodonor ligands with a binaphthalene framework[J]. Tetrahedron-Asymmetry,2004,15(19):3161-3169.
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