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Axially Dissymmetric N-Thioacylated (S)-(-)-1,1'-Binaphthyl-2,2'-diamine Ligands For Copper-Catalyzed Asymmetric Michael Addition of Diethylzinc to 1,1-Unsaturated Ketone
其他题名Axially Dissymmetric N-Thioacylated (S)-(-)-1,1'-Binaphthyl-2,2'-diamine Ligands For Copper-Catalyzed Asymmetric Michael Addition of Diethylzinc to 1,1-Unsaturated Ketone
Shi M(施敏); Duan WL(段伟良); Rong GB(容国宾); Shi M(施敏)
2004
发表期刊Chirality
卷号16期号:9页码:642-651
摘要Axially chiral thioamide ligands L5, L6, L8, L11, and bis(thioamide) ligand L13 were prepared from the reaction of (S)-(-)-1,1'-binaphthyl-2,2'-diamine with acyl chlorides and phosphorus pentasulfide (P2S5). The catalytic asymmetric 1,4-addition of diethylzinc to alpha,beta-unsaturated ketones was examined using this novel chiral ligand system with 28-73% ee in moderate to good yields. (C) 2004 Wiley-Liss, Inc.
学科领域金属有机化学
部门归属中国科学院上海有机化学研究所金属有机化学国家重点实验室; 华东理工大学
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收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/9938
专题金属有机化学国家重点实验室
通讯作者Shi M(施敏)
推荐引用方式
GB/T 7714
Shi M,Duan WL,Rong GB,et al. Axially Dissymmetric N-Thioacylated (S)-(-)-1,1'-Binaphthyl-2,2'-diamine Ligands For Copper-Catalyzed Asymmetric Michael Addition of Diethylzinc to 1,1-Unsaturated Ketone[J]. Chirality,2004,16(9):642-651.
APA Shi M,Duan WL,Rong GB,&施敏.(2004).Axially Dissymmetric N-Thioacylated (S)-(-)-1,1'-Binaphthyl-2,2'-diamine Ligands For Copper-Catalyzed Asymmetric Michael Addition of Diethylzinc to 1,1-Unsaturated Ketone.Chirality,16(9),642-651.
MLA Shi M,et al."Axially Dissymmetric N-Thioacylated (S)-(-)-1,1'-Binaphthyl-2,2'-diamine Ligands For Copper-Catalyzed Asymmetric Michael Addition of Diethylzinc to 1,1-Unsaturated Ketone".Chirality 16.9(2004):642-651.
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