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学科主题: 金属有机化学
题名: Axially Dissymmetric N-Thioacylated (S)-(-)-1,1'-Binaphthyl-2,2'-diamine Ligands For Copper-Catalyzed Asymmetric Michael Addition of Diethylzinc to 1,1-Unsaturated Ketone
其他题名: Axially Dissymmetric N-Thioacylated (S)-(-)-1,1'-Binaphthyl-2,2'-diamine Ligands For Copper-Catalyzed Asymmetric Michael Addition of Diethylzinc to 1,1-Unsaturated Ketone
作者: Shi M(施敏) ; Duan WL(段伟良) ; Rong GB(容国宾)
通讯作者: 施敏
刊名: Chirality
发表日期: 2004
卷: 16, 期:9, 页:642-651
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学国家重点实验室; 华东理工大学
英文摘要: Axially chiral thioamide ligands L5, L6, L8, L11, and bis(thioamide) ligand L13 were prepared from the reaction of (S)-(-)-1,1'-binaphthyl-2,2'-diamine with acyl chlorides and phosphorus pentasulfide (P2S5). The catalytic asymmetric 1,4-addition of diethylzinc to alpha,beta-unsaturated ketones was examined using this novel chiral ligand system with 28-73% ee in moderate to good yields. (C) 2004 Wiley-Liss, Inc.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9938
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shi M,Duan WL,Rong GB. Axially Dissymmetric N-Thioacylated (S)-(-)-1,1'-Binaphthyl-2,2'-diamine Ligands For Copper-Catalyzed Asymmetric Michael Addition of Diethylzinc to 1,1-Unsaturated Ketone[J]. Chirality,2004,16(9):642-651.
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