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学科主题: 金属有机化学
题名: Ring-expansion of MCPs in the presence of DIAD or DEAD and Lewis acids
其他题名: DIAD or DEAD和Lewis酸存在下的亚甲基环丙烷的扩环反应
作者: Shao LX(邵黎雄) ; Shi M(施敏)
通讯作者: 施敏
刊名: Eur. J. Org. Chem.
发表日期: 2004
期: 2, 页:426-430
收录类别: SCI
部门归属: 华东理工大学; 中国科学院上海有机化学研究所金属有机化学实验室
英文摘要: Treatment of methylenecyclopropanes (MCPs) with DIAD or DEAD in MeCN under mild conditions in the presence of Lewis acid Zr(OTf)(4) gave the cyclobutanone ring-expansion products in good to high yields based on the employed DIAD or DEAD. From a deuterium labeling experiment, the oxygen atom is derived from ambient water. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000188531600020
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9930
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shao LX,Shi M. Ring-expansion of MCPs in the presence of DIAD or DEAD and Lewis acids[J]. Eur. J. Org. Chem.,2004(2):426-430.
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