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学科主题: 金属有机化学
题名: Highly efficient aza-Baylis-Hillman reaction of N-tosylated imines with MVK, acrolein, and phenyl acrylate or alpha-naphthyl acrylate: Lewis base effects and a convenient method to synthesize alpha,beta-unsaturated beta-amino carbonyl compounds
其他题名: 磺酰亚胺和丁烯酮, 丙烯醛, 丙烯酸苯酯和萘酯的高效aza-Baylis-Hillman反应: Lewis碱的效应和????不饱和 ?-氨基酮类化合物的简便合成法
作者: Xu YM(徐永梅) ; Shi M(施敏)
通讯作者: 施敏
刊名: J. Org. Chem.
发表日期: 2004
卷: 69, 期:2, 页:417-425
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学实验室
英文摘要: This paper describes several highly efficient aza-Baylis-Hillman reactions of N-tosylated imines with MVK, acrolein, and phenyl acrylate or alpha-naphthyl acrylate in the presence of a Lewis base. In most cases, the reaction can be completed within 1 h using the appropriate Lewis base catalyst. An efficient method to synthesize beta-amino ketones, aldehydes and esters in high yields and short reaction time has been developed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000188496300022
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9926
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Xu YM,Shi M. Highly efficient aza-Baylis-Hillman reaction of N-tosylated imines with MVK, acrolein, and phenyl acrylate or alpha-naphthyl acrylate: Lewis base effects and a convenient method to synthesize alpha,beta-unsaturated beta-amino carbonyl compounds[J]. J. Org. Chem.,2004,69(2):417-425.
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