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学科主题: 金属有机化学
题名: Chemical fixation of carbon dioxide co-catalyzed by a combination of Schiff bases or phenols and organic bases
其他题名: 席夫碱和苯酚以及有机碱共催化的CO2固定反应研究
作者: Shen YM(沈玉梅) ; Duan WL(段伟良) ; Shi M(施敏)
通讯作者: 施敏
刊名: Eur. J. Org. Chem.
发表日期: 2004
期: 14, 页:3080-3089
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学实验室; 华东理工大学
英文摘要: Binaphthyldiamino, ethyldiamino and cyclohexyldiamino Schiff bases can catalyze the reaction of epoxides with carbon dioxide in the presence of catalytic amounts of various organic bases to give the corresponding cyclic carbonates in high yields. The simplest binaphthyldiamino Schiff base, derived from the reaction of binaphthyldiamine with salicylaldehyde, gave the highest yield of cyclic carbonate. This catalytic system can be further simplified by use of a phenol instead of the Schiff base to give the corresponding cyclic carbonates in high yields as well. Mechanistic insights were obtained based on a deuterium labeling experiment. The reaction of aziridines with CO2 and epoxide with CS2 were also examined under the same reaction conditions. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
语种: 英语
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WOS记录号: WOS:000222894900015
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9914
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shen YM,Duan WL,Shi M. Chemical fixation of carbon dioxide co-catalyzed by a combination of Schiff bases or phenols and organic bases[J]. Eur. J. Org. Chem.,2004(14):3080-3089.
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