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Different reaction patterns in the Baylis-Hillman reaction of aryl aldehydes with phenyl vinyl ketone, phenyl acrylate and phenyl thioacrylate
其他题名苯基乙烯基酮,丙烯酸苯酯,丙烯酸苯硫酯的不同 Baylis-Hillman反应类型
Shi M(施敏); Li CQ(李超群); Jiang JK(蒋健康); Shi M(施敏)
2002
发表期刊Molecules
卷号7期号:10页码:721-733
摘要In the Baylis-Hillman reaction of aryl aldehydes with phenyl vinyl ketone we have observed exclusive formation of diadducts 4, and that the yields of diadduct can reach 80% with increasing amounts of phenyl vinyl ketone. On the other hand, for phenyl acrylate and phenyl thioacrylate, only the normal Baylis-Hillman adduct was obtained The effects of substitutents were also examined and a plausible reaction mechanism is proposed for the formation of compounds 4.
学科领域金属有机化学
部门归属中国科学院上海有机化学研究所金属有机化学开放实验室
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收录类别SCI
语种英语
WOS记录号WOS:000179303500001
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文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/9898
专题金属有机化学国家重点实验室
通讯作者Shi M(施敏)
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GB/T 7714
Shi M,Li CQ,Jiang JK,et al. Different reaction patterns in the Baylis-Hillman reaction of aryl aldehydes with phenyl vinyl ketone, phenyl acrylate and phenyl thioacrylate[J]. Molecules,2002,7(10):721-733.
APA Shi M,Li CQ,Jiang JK,&施敏.(2002).Different reaction patterns in the Baylis-Hillman reaction of aryl aldehydes with phenyl vinyl ketone, phenyl acrylate and phenyl thioacrylate.Molecules,7(10),721-733.
MLA Shi M,et al."Different reaction patterns in the Baylis-Hillman reaction of aryl aldehydes with phenyl vinyl ketone, phenyl acrylate and phenyl thioacrylate".Molecules 7.10(2002):721-733.
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