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学科主题: 金属有机化学
题名: The catalytic asymmetic addition of diethylzinc to N_(Diphenylphosphinoyl) Imines catalyzed by Cu(Otf)^2-chiral N-(Binaphthyl-2-yl)thiophosphoramide ligands
其他题名: 两价铜Cu(Otf)^2和硫代磷酰亚胺配替催化的二乙基对二苯基磷酰亚胺的不对称加成反应
作者: Shi M(施敏) ; Wang CJ(王春江)
通讯作者: 施敏
刊名: Adv. Synth. Catal.
发表日期: 2003
卷: 345, 期:8, 页:971-973
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: Chiral N-(binaphthyl-2-yl)thiophosphoramide L7 [O,O-diethyl 2'-(ethylamino)-1,1'-binaphthyl-2-ylamidothiophosphate] prepared from the reaction of diethyl chlorothiophosphate with ?-(+)-N-ethyl-1,1'-binaphthyl-2,2'-diamine was used as a catalytic chiral ligand in the first Cu(Otf)^2-promoted catalytic asymmetric addition of diethylzinc to N-(diphenylphosphinoyl) imines in which ~85% ee can be realized.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9874
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shi M,Wang CJ. The catalytic asymmetic addition of diethylzinc to N_(Diphenylphosphinoyl) Imines catalyzed by Cu(Otf)^2-chiral N-(Binaphthyl-2-yl)thiophosphoramide ligands[J]. Adv. Synth. Catal.,2003,345(8):971-973.
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