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学科主题: 金属有机化学
题名: Chemical fixation of carbon dioxide catalyzed by binaphthyldiamino Zn,Cu, and Co salen-Type complexes
其他题名: 联萘胺Salen型金属锌,酮和钴络合物催化的CO2固定化反应
作者: Shen YM(沈玉梅) ; Duan WL(段伟良) ; Shi M(施敏)
通讯作者: 施敏
刊名: J. Org. Chem.
发表日期: 2003
卷: 68, 期:4, 页:1559-1562
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: Binaphthyldiamino salen-type Zn,Cu, and Co complexes can efficiently catalyze reactions of epoxides with carbon dioxide in the presence of various catalytic amounts of organic bases. The simples binaphthyldiamino salen-type Zn complex gave the five-membered cyclic carbonate 2 in excellent yield in the presence of triethylamine. A Lewis acid and Lewis base cocatalyzed mechanism is proosed.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9866
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shen YM,Duan WL,Shi M. Chemical fixation of carbon dioxide catalyzed by binaphthyldiamino Zn,Cu, and Co salen-Type complexes[J]. J. Org. Chem.,2003,68(4):1559-1562.
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