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学科主题: 金属有机化学
题名: Phenol and organic bases Co-catalyzed chemical fixation of carbon dioxide with terminal epoxides to form cyclic carbonates
其他题名: 苯酚和有机碱共催化的固定CO2的反应
作者: Shen YM(沈玉梅) ; Duan WL(段伟良) ; Shi M(施敏)
通讯作者: 施敏
刊名: Adv. Synth. Catal.
发表日期: 2003
卷: 345, 期:3, 页:337-340
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: Phenol can efficiently catalyze the reactions of terminal epoxides with carbon dioxide in the presence of catalytic amounts of various organic bases such as 4-dimethylaminopyridine (DMAP), pyridine, 1,8-dizaabicyclo[5.4.0]undec-7-ene, and triethylamine to give the corresponding five-mem-bered cyclic carbonate in high yields (initial pressure 2.57MPa; reaction temperature 120℃).p-Methoxyphenol with DMAP is the best combination to give the cyclic carbonate in the highest yield
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000181705900005
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9850
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shen YM,Duan WL,Shi M. Phenol and organic bases Co-catalyzed chemical fixation of carbon dioxide with terminal epoxides to form cyclic carbonates[J]. Adv. Synth. Catal.,2003,345(3):337-340.
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