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学科主题: 元素有机化学
题名: Reaction of arylaldehydes and N-sulfonated Imines with dimethyl acetylenedicarboxylate catalyzed by nitrogen and phosphine lewis bases
其他题名: 含氟和含膦Lowis碱催化的芳香醛和亚胺和二甲酯乙炔二酸的反应
作者: Li CZ(李超忠) ; Shi M(施敏)
通讯作者: 施敏
刊名: Org. Lett.
发表日期: 2003
卷: 5, 期:23, 页:4273-4276
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: In the reaction of arylaldehydes or N-sulfonated imines (0.5 mmol) with dimethyl acetylenedicarboxylate (DMAD) (0.6 mmol) catalyzed by pyridine or DMAP (20 mol%) we found the (E)-2-enedioic acid dimethyl ester 1 or (E)-2-[aryl-(toluene-4-sulfonylimino)methyl]-but-2-enedioic acid dimethyl ester 2 was formed in good yields at 60℃ in THF, A plausible mechanism has been proposed.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9844
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Li CZ,Shi M. Reaction of arylaldehydes and N-sulfonated Imines with dimethyl acetylenedicarboxylate catalyzed by nitrogen and phosphine lewis bases[J]. Org. Lett.,2003,5(23):4273-4276.
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