SIOC OpenIR  > 金属有机化学国家重点实验室
An exporation of asymmetric Baylis-Hillman reactions catalyzed by quinidine-derived chiral amines
其他题名奎宁丁诱导的手性胺类化合物的不对称Baylis-Hillman反应
Shi M(施敏); Jiang JK(蒋建康); Shi M(施敏)
2002
发表期刊Tetrahedron-Asymmetry
卷号13期号:17页码:1941-1947
摘要We utilized a reported quindine-derived chiral amine 1 to catalyze the asymmetric Baylis-Hillman reaction of aldehydes with methyl vinyl ketone. The enantioselectivities increase and in some cases, the absolute configuration of the Baylis-Hillman adducts can be inverted by the use of proline or lithium salt additives. The highest ee achieved is 49% with S configuration at the newly formed stereogenic centre. When using chiral amine 1 to catalyze the asymmetric Baylis-Hillman reaction of aldehydes with (α)-naphthyl acrylate, ee as high as 92% can be achieved.
学科领域金属有机化学
部门归属中国科学院上海有机化学研究所金属有机化学开放实验室
URL查看原文
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/9824
专题金属有机化学国家重点实验室
通讯作者Shi M(施敏)
推荐引用方式
GB/T 7714
Shi M,Jiang JK,Shi M. An exporation of asymmetric Baylis-Hillman reactions catalyzed by quinidine-derived chiral amines[J]. Tetrahedron-Asymmetry,2002,13(17):1941-1947.
APA Shi M,Jiang JK,&施敏.(2002).An exporation of asymmetric Baylis-Hillman reactions catalyzed by quinidine-derived chiral amines.Tetrahedron-Asymmetry,13(17),1941-1947.
MLA Shi M,et al."An exporation of asymmetric Baylis-Hillman reactions catalyzed by quinidine-derived chiral amines".Tetrahedron-Asymmetry 13.17(2002):1941-1947.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Shi M(施敏)]的文章
[Jiang JK(蒋建康)]的文章
[施敏]的文章
百度学术
百度学术中相似的文章
[Shi M(施敏)]的文章
[Jiang JK(蒋建康)]的文章
[施敏]的文章
必应学术
必应学术中相似的文章
[Shi M(施敏)]的文章
[Jiang JK(蒋建康)]的文章
[施敏]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。