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The first synthesis and isolation of‘Bis(aryloxy)phosphorothioylsulfenyl iodides’(=Bis(aryloxy)phosphinesulfenyl iodide P-Sulfides) from the jreaction of S,S'-(Diphenylstannylene)O,O,O,O',O'-tetraaryl bis[phosphorodithioates](=[(Ddiphenylstannylene)bis(thio)]bis[bis(aryloxy)phosphine P-Sulfides])with N-lodosuccinimide
其他题名二苯基氧膦硫代硫膦酰碘化合物的合成与分离
施敏; 加藤晋二
2002
发表期刊Helv. Chim. Acta
卷号85期号:8页码:2559-2563
其他摘要S,S'-(Diphenylstannylene)O,O,O,O',O'-tetraaryl bis[phosphorodithioates](=[(Ddiphenylstannylene)bis(thio)]bis[bis(aryloxy)phosphine P-Sulfides])with N-lodosuccinimide]) 5 react with N-iodosuccinimide (NIS) in CH^2Cl^2 at -30° under A to give‘bis(aryloxy)phosphorothioylsulfenyl iodides'(-bis(aryloxy)phosphinesulfenyl iodide P-sulfides) 6 (scheme 3), which can readily react in situ with 4-methylbenzenecarboditioic acid, thiol, and cyclohexene to afford the corresponding unsymmetrical disulfides and the adduct in good yields as the novel electrophilic dithiophosphorylating reagents (Schemes 4 and 5 ). By adding hexane into the solution at -30° after reaction of 5 with NIS, the 'phosphorothioylsulfenyl iodides' 6 can be isolated as yellow solids in good yields (see Table).
学科领域金属有机化学
部门归属中国科学院上海有机化学研究所金属有机化学开放实验室; 歧阜大学
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收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/9820
专题金属有机化学国家重点实验室
通讯作者施敏
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施敏,加藤晋二. The first synthesis and isolation of‘Bis(aryloxy)phosphorothioylsulfenyl iodides’(=Bis(aryloxy)phosphinesulfenyl iodide P-Sulfides) from the jreaction of S,S'-(Diphenylstannylene)O,O,O,O',O'-tetraaryl bis[phosphorodithioates](=[(Ddiphenylstannylene)bis(thio)]bis[bis(aryloxy)phosphine P-Sulfides])with N-lodosuccinimide[J]. Helv. Chim. Acta,2002,85(8):2559-2563.
APA 施敏,&加藤晋二.(2002).The first synthesis and isolation of‘Bis(aryloxy)phosphorothioylsulfenyl iodides’(=Bis(aryloxy)phosphinesulfenyl iodide P-Sulfides) from the jreaction of S,S'-(Diphenylstannylene)O,O,O,O',O'-tetraaryl bis[phosphorodithioates](=[(Ddiphenylstannylene)bis(thio)]bis[bis(aryloxy)phosphine P-Sulfides])with N-lodosuccinimide.Helv. Chim. Acta,85(8),2559-2563.
MLA 施敏,et al."The first synthesis and isolation of‘Bis(aryloxy)phosphorothioylsulfenyl iodides’(=Bis(aryloxy)phosphinesulfenyl iodide P-Sulfides) from the jreaction of S,S'-(Diphenylstannylene)O,O,O,O',O'-tetraaryl bis[phosphorodithioates](=[(Ddiphenylstannylene)bis(thio)]bis[bis(aryloxy)phosphine P-Sulfides])with N-lodosuccinimide".Helv. Chim. Acta 85.8(2002):2559-2563.
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