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学科主题: 金属有机化学
题名: The first synthesis and isolation of‘Bis(aryloxy)phosphorothioylsulfenyl iodides’(=Bis(aryloxy)phosphinesulfenyl iodide P-Sulfides) from the jreaction of S,S'-(Diphenylstannylene)O,O,O,O',O'-tetraaryl bis[phosphorodithioates](=[(Ddiphenylstannylene)bis(thio)]bis[bis(aryloxy)phosphine P-Sulfides])with N-lodosuccinimide
其他题名: 二苯基氧膦硫代硫膦酰碘化合物的合成与分离
作者: Shi M(施敏) ; 加藤晋二
通讯作者: 施敏
刊名: Helv. Chim. Acta
发表日期: 2002
卷: 85, 期:8, 页:2559-2563
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室; 歧阜大学
英文摘要: S,S'-(Diphenylstannylene)O,O,O,O',O'-tetraaryl bis[phosphorodithioates](=[(Ddiphenylstannylene)bis(thio)]bis[bis(aryloxy)phosphine P-Sulfides])with N-lodosuccinimide]) 5 react with N-iodosuccinimide (NIS) in CH^2Cl^2 at -30° under A to give‘bis(aryloxy)phosphorothioylsulfenyl iodides'(-bis(aryloxy)phosphinesulfenyl iodide P-sulfides) 6 (scheme 3), which can readily react in situ with 4-methylbenzenecarboditioic acid, thiol, and cyclohexene to afford the corresponding unsymmetrical disulfides and the adduct in good yields as the novel electrophilic dithiophosphorylating reagents (Schemes 4 and 5 ). By adding hexane into the solution at -30° after reaction of 5 with NIS, the 'phosphorothioylsulfenyl iodides' 6 can be isolated as yellow solids in good yields (see Table).
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9820
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shi M,加藤晋二. The first synthesis and isolation of‘Bis(aryloxy)phosphorothioylsulfenyl iodides’(=Bis(aryloxy)phosphinesulfenyl iodide P-Sulfides) from the jreaction of S,S'-(Diphenylstannylene)O,O,O,O',O'-tetraaryl bis[phosphorodithioates](=[(Ddiphenylstannylene)bis(thio)]bis[bis(aryloxy)phosphine P-Sulfides])with N-lodosuccinimide[J]. Helv. Chim. Acta,2002,85(8):2559-2563.
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