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学科主题: 金属有机化学
题名: Diastereoselective Baylis-Hillman type reactions of chiral non-racemic N-sulfinimines with cyclopent-2-en-1-one
其他题名: 手性磺酰亚胺和环戊烯酮的非对映选择性Baylis-Hillman的反应
作者: Shi M(施敏) ; Xu YM(徐永梅)
通讯作者: 施敏
刊名: Tetrahedron-Asymmetry
发表日期: 2002
卷: 13, 期:11, 页:1195-1200
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: In the Baylis-Hillman type reaction of chiral non-racemicN-sulfinimines 1 with cyclopent-2-1one, we found that in the presence of a catlytic amount of the Lewis base PhPMe^2(10 mol%), diastereoselective reaction could be achieved in toluene at room temperature to give the normal Baylis-Hillman adducts 2 in good yields and high diastereoselectivities.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000177072100014
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9812
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shi M,Xu YM. Diastereoselective Baylis-Hillman type reactions of chiral non-racemic N-sulfinimines with cyclopent-2-en-1-one[J]. Tetrahedron-Asymmetry,2002,13(11):1195-1200.
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