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学科主题: 金属有机化学
题名: Boron(III) tribromide or titanium (IV) bromide and lewis base promoted Baylis-Hillman reaction
其他题名: 三溴化硼和四溴化钛及Lewis碱促进的Baylis-Hillman反应
作者: Shi M(施敏) ; Cui SC(崔世聪)
通讯作者: 施敏
刊名: Chin. J. Chem.
发表日期: 2002
卷: 20, 期:3, 页:277-285
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: In was found that, when the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone was carried out at below -20℃ in the presence of boron (III) tribromide or titanium (IV) bromide using a catalytic amount of lewis base such as amine, the brominated compounds and the Baylis-Hillman adducts could be obtained as the major products in good yields for various aryl aldehydes. But at room temperature, the elimination products were the major products. In addition the palladium catalyzed allylic substitution reaction of the elimination products were also examined.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9786
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shi M,Cui SC. Boron(III) tribromide or titanium (IV) bromide and lewis base promoted Baylis-Hillman reaction[J]. Chin. J. Chem.,2002,20(3):277-285.
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