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Boron(III) tribromide or titanium (IV) bromide and lewis base promoted Baylis-Hillman reaction
其他题名三溴化硼和四溴化钛及Lewis碱促进的Baylis-Hillman反应
Shi M(施敏); Cui SC(崔世聪); Shi M(施敏)
2002
发表期刊Chin. J. Chem.
卷号20期号:3页码:277-285
摘要In was found that, when the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone was carried out at below -20℃ in the presence of boron (III) tribromide or titanium (IV) bromide using a catalytic amount of lewis base such as amine, the brominated compounds and the Baylis-Hillman adducts could be obtained as the major products in good yields for various aryl aldehydes. But at room temperature, the elimination products were the major products. In addition the palladium catalyzed allylic substitution reaction of the elimination products were also examined.
学科领域金属有机化学
部门归属中国科学院上海有机化学研究所金属有机化学开放实验室
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收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/9786
专题金属有机化学国家重点实验室
通讯作者Shi M(施敏)
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GB/T 7714
Shi M,Cui SC,Shi M. Boron(III) tribromide or titanium (IV) bromide and lewis base promoted Baylis-Hillman reaction[J]. Chin. J. Chem.,2002,20(3):277-285.
APA Shi M,Cui SC,&施敏.(2002).Boron(III) tribromide or titanium (IV) bromide and lewis base promoted Baylis-Hillman reaction.Chin. J. Chem.,20(3),277-285.
MLA Shi M,et al."Boron(III) tribromide or titanium (IV) bromide and lewis base promoted Baylis-Hillman reaction".Chin. J. Chem. 20.3(2002):277-285.
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