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New discovery in the traditional Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone
Alternative Title芳香醛和丁烯酮在传统的Baylis-Hillman反应中的新发现
Shi M(施敏); Li CQ(李超群); Jiang JK(蒋建康); Shi M(施敏)
2001
Source PublicationChem. Commun.
Issue9Pages:833-834
AbstractIn the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone, we found that, besides the normal Baylis-Hillman reaction product 1, the diadduct 2 can also be formed at the same time and the yield of 2 can reach 55% by increasing the amount of methyl vinyl ketone; but for acrylonitrile and methyl acylate, only the normal Baylis-Hillman adduct was obtained; the substitutent's effects were also examined and a plausible reaction mechanis was proposed for the formation of 2.
Subject Area金属有机化学
Department中国科学院上海有机化学研究所金属有机化学开放实验室
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Indexed BySCI
Language英语
WOS IDWOS:000168357200020
Citation statistics
Cited Times:55[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/9756
Collection金属有机化学国家重点实验室
Corresponding AuthorShi M(施敏)
Recommended Citation
GB/T 7714
Shi M,Li CQ,Jiang JK,et al. New discovery in the traditional Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone[J]. Chem. Commun.,2001(9):833-834.
APA Shi M,Li CQ,Jiang JK,&施敏.(2001).New discovery in the traditional Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone.Chem. Commun.(9),833-834.
MLA Shi M,et al."New discovery in the traditional Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone".Chem. Commun. .9(2001):833-834.
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