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学科主题: 天然产物有机化学
题名: A facile route to bulladecin-type-acetogenins-total synthesis of asimilobin and correction of the configuration of its tetrahydrofuran segment
其他题名: Bulladecin 型蕃荔枝内酯类化合物的合成-Asimilobin的全合成和其四氢呋喃环部分绝对构型的更正
作者: Wang ZM(王志敏) ; Tian SK(田仕凯) ; Shi M(施敏)
通讯作者: 王志敏 ; 施敏
刊名: Eur. J. Org. Chem.
发表日期: 2000
期: 2, 页:349-356
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The most efficient method for the synthesis of the trans/threo/trans-bis(tetrahydrofuran)(THF) ring unit was established, and the first total synthesis of (-)-asimilogin and its diastereomer was then accomplished in twelve and fourteen steps, respectively, from trans-1,5,9-decatriene, by a convergent route with Wittig reaction as the key step. By virtue of these synthetic results, the absolute configuration of the bis(THF) unit in naturally occurring asimilobin should be corrected.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9736
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wang ZM,Tian SK,Shi M. A facile route to bulladecin-type-acetogenins-total synthesis of asimilobin and correction of the configuration of its tetrahydrofuran segment[J]. Eur. J. Org. Chem.,2000(2):349-356.
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