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学科主题: 金属有机化学
题名: Chiral diphenylselenophosphoramides; a new class of chiral ligands for the titanium (IV) alkoxide-promoted addition of diethylzinc to aldehydes
其他题名: 手性硒膦酰胺类配提的合成, 一组新型的可用于四异丙氧基钛促进的醛和二乙基锌不对称加成反应的手性
作者: Shi M(施敏) ; Sui WS(隋文盛)
通讯作者: 施敏
刊名: Tetrahedron-Asymmetry
发表日期: 2000
卷: 11, 期:3, 页:835-841
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: Chiral C^2-symmetric diphenylselenophosphoramides 1 and 2 were prepared from the reaction of diphenylselenophosphinic chloride with (1R,2R)-(-)-1,2-diaminocyclohexane and (1R,2R)-(+)-1,2-diphenylethylenediamine, respectively, in high yields. Another novel chiral ligand 3 was prepared from the reaction of diphenylselenophosphinic chloride with (R)-(+)-1,1-binaphthyl-2,2'-diamine using butyllithium as the base. The ligands were used as catalytic chiral ligands in the titanium(IV) alkoxide-promoted enantioselective addition reaction of diethylzinc to aldehydes.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9732
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shi M,Sui WS. Chiral diphenylselenophosphoramides; a new class of chiral ligands for the titanium (IV) alkoxide-promoted addition of diethylzinc to aldehydes[J]. Tetrahedron-Asymmetry,2000,11(3):835-841.
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