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Chiral diphenylselenophosphoramides; a new class of chiral ligands for the titanium (IV) alkoxide-promoted addition of diethylzinc to aldehydes
其他题名手性硒膦酰胺类配提的合成, 一组新型的可用于四异丙氧基钛促进的醛和二乙基锌不对称加成反应的手性
Shi M(施敏); Sui WS(隋文盛); Shi M(施敏)
2000
发表期刊Tetrahedron-Asymmetry
卷号11期号:3页码:835-841
摘要Chiral C^2-symmetric diphenylselenophosphoramides 1 and 2 were prepared from the reaction of diphenylselenophosphinic chloride with (1R,2R)-(-)-1,2-diaminocyclohexane and (1R,2R)-(+)-1,2-diphenylethylenediamine, respectively, in high yields. Another novel chiral ligand 3 was prepared from the reaction of diphenylselenophosphinic chloride with (R)-(+)-1,1-binaphthyl-2,2'-diamine using butyllithium as the base. The ligands were used as catalytic chiral ligands in the titanium(IV) alkoxide-promoted enantioselective addition reaction of diethylzinc to aldehydes.
学科领域金属有机化学
部门归属中国科学院上海有机化学研究所金属有机化学开放实验室
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收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/9732
专题金属有机化学国家重点实验室
通讯作者Shi M(施敏)
推荐引用方式
GB/T 7714
Shi M,Sui WS,Shi M. Chiral diphenylselenophosphoramides; a new class of chiral ligands for the titanium (IV) alkoxide-promoted addition of diethylzinc to aldehydes[J]. Tetrahedron-Asymmetry,2000,11(3):835-841.
APA Shi M,Sui WS,&施敏.(2000).Chiral diphenylselenophosphoramides; a new class of chiral ligands for the titanium (IV) alkoxide-promoted addition of diethylzinc to aldehydes.Tetrahedron-Asymmetry,11(3),835-841.
MLA Shi M,et al."Chiral diphenylselenophosphoramides; a new class of chiral ligands for the titanium (IV) alkoxide-promoted addition of diethylzinc to aldehydes".Tetrahedron-Asymmetry 11.3(2000):835-841.
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