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学科主题: 天然产物有机化学
题名: A simple synthetic method for chiral 1,2-epoxides and the total synthesis of a chiral pheromone epoxide
其他题名: 手性1,2-环氧化合物的合成以及手性昆虫信息素的简便合成法
作者: Zhang ZB(张智波) ; Wang ZM(王志敏) ; Wang YX(王毓秀) ; Liu HQ(刘汉泉) ; Lei GX(雷桂馨) ; Shi M(施敏)
通讯作者: 王志敏 ; 施敏
刊名: J. Chem. Soc.-Perkin Trans. 1
发表日期: 2000
期: 1, 页:53-57
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: Chiral 1,2-epoxyalkan-3-ol tosyl esters 4a-h were successfully synthesized from alkynols or allyl chlorides in three steps using Sharpless AD reaction as a key step in good yields. The chiral insect pheromone epoxide (6Z,9S,10R)-9,10-epoxyhenicos-6-ene 9 was thus smoothly synthesized from the corresponding key intermediate 4g.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000084864000007
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9730
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhang ZB,Wang ZM,Wang YX,et al. A simple synthetic method for chiral 1,2-epoxides and the total synthesis of a chiral pheromone epoxide[J]. J. Chem. Soc.-Perkin Trans. 1,2000(1):53-57.
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