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学科主题: 金属有机化学
题名: An unexpected carbon dioxide insertion in the reaction of trans-2,4-Disubstituted azetidine, trans-2,5-disubstituted pyrrolidine, ortrans-2,6-disubstituted piperidine with diphenylthiophosphinic chloride and diphenylselenophosphinic chloride
其他题名: 反式-2,4-二取代氮环丁烷,反式-2,5-二取代吡咯烷, 以及反式-2,6-哌啶烷和二苯基膦酰氯反应时, 一个出乎意料的CO^2插入反应
作者: Shi M(施敏) ; Jiang JK(蒋建康) ; Shen YM(沈玉梅) ; Feng YS(冯言枢) ; Lei GX(雷桂馨)
通讯作者: 施敏
刊名: J. Org. Chem.
发表日期: 2000
卷: 65, 期:11, 页:3443-3448
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: In the reaction of trans-2,4-disubstituted azetidine, trans-2,5-disubstituted pyrrolidine, or trans-2,6-disubstituted poperdine with diphenylthiophosphinic chloride or diphenylselenophosphine chloride in acetronitrile in the presence of potassium carbonate at room temperature, an unexpected carbon dioxide insertion produced carbamic diphenylthiophosphinic or diphenylselenophosphinic anhydride in good yield. The same product could be also obtained when the reaction was carried out under carbon dioxide atmosphere using potassium hydroxide or triethylamine as a base. This is a very simple reaction process related to the fixation of carbon dioxide without a metal catalyst.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/9712
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shi M,Jiang JK,Shen YM,et al. An unexpected carbon dioxide insertion in the reaction of trans-2,4-Disubstituted azetidine, trans-2,5-disubstituted pyrrolidine, ortrans-2,6-disubstituted piperidine with diphenylthiophosphinic chloride and diphenylselenophosphinic chloride[J]. J. Org. Chem.,2000,65(11):3443-3448.
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