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An unexpected carbon dioxide insertion in the reaction of trans-2,4-Disubstituted azetidine, trans-2,5-disubstituted pyrrolidine, ortrans-2,6-disubstituted piperidine with diphenylthiophosphinic chloride and diphenylselenophosphinic chloride
其他题名反式-2,4-二取代氮环丁烷,反式-2,5-二取代吡咯烷, 以及反式-2,6-哌啶烷和二苯基膦酰氯反应时, 一个出乎意料的CO^2插入反应
Shi M(施敏); Jiang JK(蒋建康); Shen YM(沈玉梅); Feng YS(冯言枢); Lei GX(雷桂馨); Shi M(施敏)
2000
发表期刊J. Org. Chem.
卷号65期号:11页码:3443-3448
摘要In the reaction of trans-2,4-disubstituted azetidine, trans-2,5-disubstituted pyrrolidine, or trans-2,6-disubstituted poperdine with diphenylthiophosphinic chloride or diphenylselenophosphine chloride in acetronitrile in the presence of potassium carbonate at room temperature, an unexpected carbon dioxide insertion produced carbamic diphenylthiophosphinic or diphenylselenophosphinic anhydride in good yield. The same product could be also obtained when the reaction was carried out under carbon dioxide atmosphere using potassium hydroxide or triethylamine as a base. This is a very simple reaction process related to the fixation of carbon dioxide without a metal catalyst.
学科领域金属有机化学
部门归属中国科学院上海有机化学研究所金属有机化学开放实验室
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收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/9712
专题金属有机化学国家重点实验室
通讯作者Shi M(施敏)
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GB/T 7714
Shi M,Jiang JK,Shen YM,et al. An unexpected carbon dioxide insertion in the reaction of trans-2,4-Disubstituted azetidine, trans-2,5-disubstituted pyrrolidine, ortrans-2,6-disubstituted piperidine with diphenylthiophosphinic chloride and diphenylselenophosphinic chloride[J]. J. Org. Chem.,2000,65(11):3443-3448.
APA Shi M,Jiang JK,Shen YM,Feng YS,Lei GX,&施敏.(2000).An unexpected carbon dioxide insertion in the reaction of trans-2,4-Disubstituted azetidine, trans-2,5-disubstituted pyrrolidine, ortrans-2,6-disubstituted piperidine with diphenylthiophosphinic chloride and diphenylselenophosphinic chloride.J. Org. Chem.,65(11),3443-3448.
MLA Shi M,et al."An unexpected carbon dioxide insertion in the reaction of trans-2,4-Disubstituted azetidine, trans-2,5-disubstituted pyrrolidine, ortrans-2,6-disubstituted piperidine with diphenylthiophosphinic chloride and diphenylselenophosphinic chloride".J. Org. Chem. 65.11(2000):3443-3448.
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