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New Fluoropolymers Having Both Low Water Uptake and a Low Dielectric Constant
其他题名具有低吸水率和低介电常数的新含氟聚合物
He FK(贺凤开)1; Jin KK(金凯凯)1; Wang JJ(王佳佳)1; LUO YIJIE1; Sun J(孙晶)1; Fang Q(房强)1
2015
发表期刊Macromol. Chem. Phys.
卷号216期号:23页码:2302-2308
摘要Polymers with both low water uptake and a low dielectric constant have seen interest from both the electronic and microelectronic industries for several years. They play a crucial role in maintaining the good operating situation of devices, whereas most other materials are unsatisfactory. In this contribution, two new fluoropolymers are reported, which are derived from the thermo-crosslinking reaction of functional monomers containing perfluorocyclobutane and benzocyclobutene moieties. These polymers show water uptake ranging from 0.11 to 0.31% after immersion in boiling water (near 98 degrees C) for 96 h, and exhibit dielectric constants (k) of below 2.4 at a range of frequencies from 0.1 MHz to 30 MHz. In contrast, a comparative polymer without perfluorocyclobutane units has a k value of more than 2.70 and water uptake of 0.67%, respectively, suggesting that the low water absorption and dielectric constants of the fluoropolymers can be attributed to the existence of perfluorocyclobutane groups in the molecular backbone. These results also indicate that the properties of the fluoropolymers are superior to these of the most commercial polymeric low-k materials, implying that these fluoropolymers could be used as the varnish for enameled wire in the electrical industry and as encapsulation resins in the microelectronics industry.
文章类型论文
学科领域高分子化学
DOI10.1002/macp.201500394
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收录类别SCI
语种英语
WOS记录号WOS:000366391600008
引用统计
被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/39865
专题高分子材料研究室
通讯作者Fang Q(房强)
作者单位1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.中科院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室
推荐引用方式
GB/T 7714
He FK,Jin KK,Wang JJ,et al. New Fluoropolymers Having Both Low Water Uptake and a Low Dielectric Constant[J]. Macromol. Chem. Phys.,2015,216(23):2302-2308.
APA 贺凤开,金凯凯,王佳佳,LUO YIJIE,孙晶,&房强.(2015).New Fluoropolymers Having Both Low Water Uptake and a Low Dielectric Constant.Macromol. Chem. Phys.,216(23),2302-2308.
MLA 贺凤开,et al."New Fluoropolymers Having Both Low Water Uptake and a Low Dielectric Constant".Macromol. Chem. Phys. 216.23(2015):2302-2308.
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