中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 高分子材料研究室  > 期刊论文
学科主题: 高分子化学
题名: Synthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer
其他题名: Synthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer
作者: Lu GL(陆国林)1; Jiang XJ(蒋晓军)1; Li YJ(李永军)1; Lv XL(吕绪良)1; Huang XY(黄晓宇)1
通讯作者: 吕绪良 ; 黄晓宇
刊名: RSC Adv.
发表日期: 2015
DOI: 10.1039/c5ra14302k
卷: 5, 期:91, 页:74947-74952
收录类别: SCI
文章类型: 论文
英文摘要: Two well-defined perfluorocyclobutyl aryl ether-based amphiphilic graft copolymers containing a hydrophobic poly(2-methyl-1,4-bistrifluorovinyloxybenzene) (PMBTFVB) backbone and hydrophilic poly(N-isopropylacrylamide) (PNIPAM) side chains were synthesized via sequential thermal step-growth [2 pi + 2 pi] cycloaddition polymerization of 2-methyl-1,4-bistrifluorovinyloxybenzene and atom transfer radical polymerization (ATRP) of N-isopropylacrylamide (NIPAM). PMBTFVB homopolymer was converted to PMBTFVB-Cl macroinitiator by monochlorination of the pendant methyls with N-chlorosuccinimide and benzoyl peroxide. A grafting-from strategy was then adopted for preparing well-defined PMBTFVB-g-PNIPAM graft copolymers with narrow molecular weight distributions (M-w/M-n < 1.30) via ATRP of NIPAM, which was initiated by the Cl-containing macroinitiator. The critical micelle concentration (cmc) was determined by a fluorescence probe technique and the effects of salinity on the cmc of PMBTFVB-g-PNIPAM graft copolymer were also investigated.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000361116500096
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39857
Appears in Collections:高分子材料研究室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2015480.pdf(847KB)期刊论文作者接受稿开放获取View Download

作者单位: 1.中科院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室
2.解放军理工大学

Recommended Citation:
Lu GL,Jiang XJ,Li YJ,et al. Synthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer[J]. RSC Adv.,2015,5(91):74947-74952.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[陆国林]'s Articles
[蒋晓军]'s Articles
[李永军]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[陆国林]‘s Articles
[蒋晓军]‘s Articles
[李永军]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2015480.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace