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Synthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer
Alternative TitleSynthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer
Lu GL(陆国林)1; Jiang XJ(蒋晓军)1; Li YJ(李永军)1; Lv XL(吕绪良)1; Huang XY(黄晓宇)1
2015
Source PublicationRSC Adv.
Volume5Issue:91Pages:74947-74952
AbstractTwo well-defined perfluorocyclobutyl aryl ether-based amphiphilic graft copolymers containing a hydrophobic poly(2-methyl-1,4-bistrifluorovinyloxybenzene) (PMBTFVB) backbone and hydrophilic poly(N-isopropylacrylamide) (PNIPAM) side chains were synthesized via sequential thermal step-growth [2 pi + 2 pi] cycloaddition polymerization of 2-methyl-1,4-bistrifluorovinyloxybenzene and atom transfer radical polymerization (ATRP) of N-isopropylacrylamide (NIPAM). PMBTFVB homopolymer was converted to PMBTFVB-Cl macroinitiator by monochlorination of the pendant methyls with N-chlorosuccinimide and benzoyl peroxide. A grafting-from strategy was then adopted for preparing well-defined PMBTFVB-g-PNIPAM graft copolymers with narrow molecular weight distributions (M-w/M-n < 1.30) via ATRP of NIPAM, which was initiated by the Cl-containing macroinitiator. The critical micelle concentration (cmc) was determined by a fluorescence probe technique and the effects of salinity on the cmc of PMBTFVB-g-PNIPAM graft copolymer were also investigated.
Subtype论文
Subject Area高分子化学
DOI10.1039/c5ra14302k
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000361116500096
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39857
Collection高分子材料研究室
Corresponding AuthorLv XL(吕绪良); Huang XY(黄晓宇)
Affiliation1.中科院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室
2.解放军理工大学
Recommended Citation
GB/T 7714
Lu GL,Jiang XJ,Li YJ,et al. Synthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer[J]. RSC Adv.,2015,5(91):74947-74952.
APA 陆国林,蒋晓军,李永军,吕绪良,&黄晓宇.(2015).Synthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer.RSC Adv.,5(91),74947-74952.
MLA 陆国林,et al."Synthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer".RSC Adv. 5.91(2015):74947-74952.
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