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Changing to Poly(rod-coil) Polymers: A Promising Way for an Optoelectronic Compound to Improve Its Film Formation
Alternative Title改为多节棍型聚合物是光电化合物提高其成膜性的理想途径
Shao W(邵伟)1; Liang L(梁龙)1; Xiang X(项宣)1; Li HJ(李红娇)1; Zhao FG(赵福刚)1; Li WS(李维实)1
2015
Source PublicationChin. J. Chem.
Volume33Issue:8Pages:847-851
AbstractGood film formation is one of basic requirements for organic optoelectronic materials to achieve the capability for fabrication of large area devices. Small molecular optoelectronic compounds have a definite chemical structure and clear device performance, and thus are welcomed in the field. However, they are generally suffering from poor film formation, especially in a large area. For addressing it, this contribution proposes and demonstrates a strategy, that is, changing them into poly(rod-coil) polymers. With one optoelectronic compound [BDT(DTBT)(2)] and three poly(rod-coil) polymers (P1, P2, and P3) having different non-conjugated coil segments as examples, the work clearly shows that the change to poly(rod-coil) polymers keeps many basic optoelectronic properties of the reference compound, including light absorption in solution, bandgap and frontier orbital energy levels, but suppresses strong intermolecular interactions and crystalline structure in film state. Further comparisons on film formation quality on glass and ITO glass illustrate that all the three polymers have a better film formation property than the reference compound.
Subtype论文
Subject Area高分子化学
DOI10.1002/cjoc.201500179
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000360221600005
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39854
Collection高分子材料研究室
Corresponding AuthorLi WS(李维实)
Affiliation1.浙江理工大学
2.中科院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室
Recommended Citation
GB/T 7714
Shao W,Liang L,Xiang X,et al. Changing to Poly(rod-coil) Polymers: A Promising Way for an Optoelectronic Compound to Improve Its Film Formation[J]. Chin. J. Chem.,2015,33(8):847-851.
APA 邵伟,梁龙,项宣,李红娇,赵福刚,&李维实.(2015).Changing to Poly(rod-coil) Polymers: A Promising Way for an Optoelectronic Compound to Improve Its Film Formation.Chin. J. Chem.,33(8),847-851.
MLA 邵伟,et al."Changing to Poly(rod-coil) Polymers: A Promising Way for an Optoelectronic Compound to Improve Its Film Formation".Chin. J. Chem. 33.8(2015):847-851.
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