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Silver-Catalyzed Decarboxylative Radical Azidation of Aliphatic Carboxylic Acids in Aqueous Solution
Alternative Title银催化脂肪酸在水相中的自由基脱羧叠氮化
Liu C(刘超)1; Wang XQ(王晓卿)1; Li ZD(李兆栋)1; Cui L(崔磊)1; Li CZ(李超忠)1
2015
Source PublicationJ. Am. Chem. Soc.
Volume137Issue:31Pages:9820-9823
AbstractWe report herein an efficient and general method for the decarboxylative azidation of aliphatic carboxylic acids. Thus, with AgNO3 as the catalyst and (KS2O8)-S-2 as the oxidant, the reactions of various aliphatic carboxylic acids with tosyl azide or pyridine-3-sulfonyl azide in aqueous CH3CN solution afforded the corresponding alkyl azides under mild conditions. A broad substrate scope and wide functional group compatibility were observed. A radical mechanism is proposed for this site-specific azidation.
Subtype论文
Subject Area高分子化学
DOI10.1021/jacs.5b06821
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000359613300016
Citation statistics
Cited Times:83[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39852
Collection高分子材料研究室
Corresponding AuthorLi CZ(李超忠)
Affiliation1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.宁波工程学院
Recommended Citation
GB/T 7714
Liu C,Wang XQ,Li ZD,et al. Silver-Catalyzed Decarboxylative Radical Azidation of Aliphatic Carboxylic Acids in Aqueous Solution[J]. J. Am. Chem. Soc.,2015,137(31):9820-9823.
APA 刘超,王晓卿,李兆栋,崔磊,&李超忠.(2015).Silver-Catalyzed Decarboxylative Radical Azidation of Aliphatic Carboxylic Acids in Aqueous Solution.J. Am. Chem. Soc.,137(31),9820-9823.
MLA 刘超,et al."Silver-Catalyzed Decarboxylative Radical Azidation of Aliphatic Carboxylic Acids in Aqueous Solution".J. Am. Chem. Soc. 137.31(2015):9820-9823.
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