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学科主题: 高分子化学
题名: Silver-Catalyzed Decarboxylative Radical Azidation of Aliphatic Carboxylic Acids in Aqueous Solution
其他题名: 银催化脂肪酸在水相中的自由基脱羧叠氮化
作者: Liu C(刘超)1; Wang XQ(王晓卿)1; Li ZD(李兆栋)1; Cui L(崔磊)1; Li CZ(李超忠)1
通讯作者: 李超忠
刊名: J. Am. Chem. Soc.
发表日期: 2015
DOI: 10.1021/jacs.5b06821
卷: 137, 期:31, 页:9820-9823
收录类别: SCI
文章类型: 论文
英文摘要: We report herein an efficient and general method for the decarboxylative azidation of aliphatic carboxylic acids. Thus, with AgNO3 as the catalyst and (KS2O8)-S-2 as the oxidant, the reactions of various aliphatic carboxylic acids with tosyl azide or pyridine-3-sulfonyl azide in aqueous CH3CN solution afforded the corresponding alkyl azides under mild conditions. A broad substrate scope and wide functional group compatibility were observed. A radical mechanism is proposed for this site-specific azidation.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000359613300016
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39852
Appears in Collections:高分子材料研究室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.宁波工程学院

Recommended Citation:
Liu C,Wang XQ,Li ZD,et al. Silver-Catalyzed Decarboxylative Radical Azidation of Aliphatic Carboxylic Acids in Aqueous Solution[J]. J. Am. Chem. Soc.,2015,137(31):9820-9823.
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