中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 高分子材料研究室  > 期刊论文
学科主题: 高分子化学
题名: Construction of semi-fluorinated amphiphilic graft copolymer bearing a poly(2-methyl-1,4-bistrifluorovinyloxybenzene) backbone and poly(ethylene glycol) side chains via the grafting-onto strategy
其他题名: Construction of semi-fluorinated amphiphilic graft copolymer bearing a poly(2-methyl-1,4-bistrifluorovinyloxybenzene) backbone and poly(ethylene glycol) side chains via the grafting-onto strategy
作者: Lu GL(陆国林)1; Liu H(刘好)1; Gao HF(高海峰)1; Feng C(冯纯)1; Li YJ(李永军)1; Huang XY(黄晓宇)1
通讯作者: 高海峰 ; 冯纯 ; 黄晓宇
刊名: RSC Adv.
发表日期: 2015
DOI: 10.1039/c5ra02377g
卷: 5, 期:50, 页:39668-39676
收录类别: SCI
文章类型: 论文
英文摘要: Amphiphilic graft copolymers bearing a hydrophobic poly(2-methyl-1,4-bistrifluorovinyloxybenzene) (PMBTFVB) backbone and hydrophilic poly(ethylene glycol) (PEG) side chains were synthesized through the Williamson reaction between the hydroxyl end group of PEG and the pendant benzyl bromide functionality of the backbone introduced through the mono-bromination of the pendant methyls on the backbone by using N-bromosuccinimide and benzoyl peroxide, via the grafting-onto strategy. Critical micelle concentrations (cmc) of these amphiphilic graft copolymers were determined by fluorescence spectroscopy using N-phenyl-1-naphthylamine as a fluorescence probe. The studies on the morphologies of self-assembled aggregates of the resulting PMBTFVB-g-PEG graft copolymers with relatively narrow molecular weight distributions (M-w/M-n = 1.26-1.39) in aqueous solution showed that the observed morphologies were obviously affected by a number of factors including the method used for preparing micelles, the concentration of the copolymer in the cosolvent, and the water content.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000354211100005
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39848
Appears in Collections:高分子材料研究室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2015296.pdf(897KB)期刊论文作者接受稿开放获取View Download

作者单位: 1.中科院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室
2.美国圣母诺特丹大学

Recommended Citation:
Lu GL,Liu H,Gao HF,et al. Construction of semi-fluorinated amphiphilic graft copolymer bearing a poly(2-methyl-1,4-bistrifluorovinyloxybenzene) backbone and poly(ethylene glycol) side chains via the grafting-onto strategy[J]. RSC Adv.,2015,5(50):39668-39676.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[陆国林]'s Articles
[刘好]'s Articles
[高海峰]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[陆国林]‘s Articles
[刘好]‘s Articles
[高海峰]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2015296.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace