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Construction of semi-fluorinated amphiphilic graft copolymer bearing a poly(2-methyl-1,4-bistrifluorovinyloxybenzene) backbone and poly(ethylene glycol) side chains via the grafting-onto strategy
其他题名Construction of semi-fluorinated amphiphilic graft copolymer bearing a poly(2-methyl-1,4-bistrifluorovinyloxybenzene) backbone and poly(ethylene glycol) side chains via the grafting-onto strategy
Lu GL(陆国林)1; Liu H(刘好)1; Gao HF(高海峰)1; Feng C(冯纯)1; Li YJ(李永军)1; Huang XY(黄晓宇)1
2015
发表期刊RSC Adv.
卷号5期号:50页码:39668-39676
摘要Amphiphilic graft copolymers bearing a hydrophobic poly(2-methyl-1,4-bistrifluorovinyloxybenzene) (PMBTFVB) backbone and hydrophilic poly(ethylene glycol) (PEG) side chains were synthesized through the Williamson reaction between the hydroxyl end group of PEG and the pendant benzyl bromide functionality of the backbone introduced through the mono-bromination of the pendant methyls on the backbone by using N-bromosuccinimide and benzoyl peroxide, via the grafting-onto strategy. Critical micelle concentrations (cmc) of these amphiphilic graft copolymers were determined by fluorescence spectroscopy using N-phenyl-1-naphthylamine as a fluorescence probe. The studies on the morphologies of self-assembled aggregates of the resulting PMBTFVB-g-PEG graft copolymers with relatively narrow molecular weight distributions (M-w/M-n = 1.26-1.39) in aqueous solution showed that the observed morphologies were obviously affected by a number of factors including the method used for preparing micelles, the concentration of the copolymer in the cosolvent, and the water content.
文章类型论文
学科领域高分子化学
DOI10.1039/c5ra02377g
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000354211100005
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被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/39848
专题高分子材料研究室
通讯作者Gao HF(高海峰); Feng C(冯纯); Huang XY(黄晓宇)
作者单位1.中科院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室
2.美国圣母诺特丹大学
推荐引用方式
GB/T 7714
Lu GL,Liu H,Gao HF,et al. Construction of semi-fluorinated amphiphilic graft copolymer bearing a poly(2-methyl-1,4-bistrifluorovinyloxybenzene) backbone and poly(ethylene glycol) side chains via the grafting-onto strategy[J]. RSC Adv.,2015,5(50):39668-39676.
APA 陆国林,刘好,高海峰,冯纯,李永军,&黄晓宇.(2015).Construction of semi-fluorinated amphiphilic graft copolymer bearing a poly(2-methyl-1,4-bistrifluorovinyloxybenzene) backbone and poly(ethylene glycol) side chains via the grafting-onto strategy.RSC Adv.,5(50),39668-39676.
MLA 陆国林,et al."Construction of semi-fluorinated amphiphilic graft copolymer bearing a poly(2-methyl-1,4-bistrifluorovinyloxybenzene) backbone and poly(ethylene glycol) side chains via the grafting-onto strategy".RSC Adv. 5.50(2015):39668-39676.
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