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Preparation of graphene/poly(2-hydroxyethyl acrylate) nanohybrid materials via an ambient temperature "grafting-from" strategy
Alternative TitlePreparation of graphene/poly(2-hydroxyethyl acrylate) nanohybrid materials via an ambient temperature "grafting-from" strategy
Liu ZZ(刘站站)1; Zhu SJ(朱绍佳)1; Li YJ(李永军)1; Li YS(李永生)1; Shi P(史萍)1; Huang Z(黄忠)1; Huang XY(黄晓宇)1
2015
Source PublicationPolym. Chem.
Volume6Issue:2Pages:311-321
AbstractGraphene has emerged to be a promising material due to its unique structure and two-dimensional and extensively conjugated surface. However, graphene tends to aggregate in an almost irreversible manner, it is therefore useful to modify carbon sheets to achieve solubility for further applications. Herein, we report a new graphene/polymer nanohybrid material, graphene/poly(2-hydroxyethyl acrylate) (G-PHEA), aiming to improve its solubility in regular solvents. The preparation of PHEA polymer brushes on the surfaces of reduced graphene oxide sheets was accomplished by in situ single-electron transfer living radical polymerization (SET-LRP) under mild conditions via the "grafting-from" strategy. Initiating groups containing graphene sheets were prepared by a diazonium reaction followed by esterification for attaching Br-containing initiating groups onto the surface of graphene. Surface-initiated SET-LRP of 2-hydroxylethyl acrylate was performed in DMSO in the presence of a Cu wire/Me6TREN catalytic system at room temperature to form G-PHEA nanohybrid material. FT-IR, XRD, Raman, TGA, AFM, and TEM measurements showed the efficient PHEA-functionalized covalent modification of graphene with good dispersibility in organic solvents and aqueous media. This kind of nanohybrid material is not cytotoxic by itself and could quickly enter into SMMC-7721 and SH-SY5Y cells.
Subtype论文
Subject Area高分子化学
DOI10.1039/c4py00903g
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000346049200016
Citation statistics
Cited Times:29[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39832
Collection高分子材料研究室
Corresponding AuthorLi YS(李永生); Shi P(史萍); Huang XY(黄晓宇)
Affiliation1.中科院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室
2.华东理工大学
3.复旦大学
Recommended Citation
GB/T 7714
Liu ZZ,Zhu SJ,Li YJ,et al. Preparation of graphene/poly(2-hydroxyethyl acrylate) nanohybrid materials via an ambient temperature "grafting-from" strategy[J]. Polym. Chem.,2015,6(2):311-321.
APA 刘站站.,朱绍佳.,李永军.,李永生.,史萍.,...&黄晓宇.(2015).Preparation of graphene/poly(2-hydroxyethyl acrylate) nanohybrid materials via an ambient temperature "grafting-from" strategy.Polym. Chem.,6(2),311-321.
MLA 刘站站,et al."Preparation of graphene/poly(2-hydroxyethyl acrylate) nanohybrid materials via an ambient temperature "grafting-from" strategy".Polym. Chem. 6.2(2015):311-321.
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