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New polymethylene-based AB(2) star copolymers synthesized via a combination of polyhomologation of ylides and atom transfer radical polymerization
Alternative Title叶立德同源聚合与ATRP聚合相结合制备新型聚亚甲基AB2星形共聚物
Xue Y(薛杨)1; Zhang SS(张双双)1; Cui K(崔崑)1; Huang J(黄晋)1; Zhao QL(赵巧玲)1; Lan P(蓝平)1; Cao SK(曹少魁)1; Ma Z(马志)1
2015
Source PublicationRSC Adv.
Volume5Issue:10Pages:7090-7097
AbstractNew polymethylene-based AB(2) star polymers with well-defined architecture and various components were synthesized using a combination of polyhomologation of ylides and atomic transfer radical polymerization (ATRP). The chain structures of polymethylene-b-(polystyrene)(2) (PM-b-(PS)(2)) and polymethylene-b-( poly(methyl methacrylate))(2) (PM-b-(PMMA)(2)) were characterized through H-1 NMR, GPC and FT-IR. The porous films of such star copolymers were fabricated via a static breath-figure (BF) process. The influence of polymer molecular weight, solution concentration and environmental temperature on the morphology of such block copolymer films was investigated. The porous surface of such a film presents hydrophobic behaviour with a static water-droplet contact angle of ca. 108 degrees. The electrospinning of PM-b-(PS)(2) was performed using CHCl3 as a solvent and the wrinkle-like polymer particles with nanopores on their surface were obtained.
Subtype论文
Subject Area高分子化学
DOI10.1039/c4ra14504f
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000347609400010
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39830
Collection高分子材料研究室
Corresponding AuthorMa Z(马志)
Affiliation1.中科院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室
2.郑州大学
3.嘉兴学院
Recommended Citation
GB/T 7714
Xue Y,Zhang SS,Cui K,et al. New polymethylene-based AB(2) star copolymers synthesized via a combination of polyhomologation of ylides and atom transfer radical polymerization[J]. RSC Adv.,2015,5(10):7090-7097.
APA 薛杨.,张双双.,崔崑.,黄晋.,赵巧玲.,...&马志.(2015).New polymethylene-based AB(2) star copolymers synthesized via a combination of polyhomologation of ylides and atom transfer radical polymerization.RSC Adv.,5(10),7090-7097.
MLA 薛杨,et al."New polymethylene-based AB(2) star copolymers synthesized via a combination of polyhomologation of ylides and atom transfer radical polymerization".RSC Adv. 5.10(2015):7090-7097.
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