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学科主题: 天然产物有机化学
题名: Direct amination of EF spiroketal in steroidal sapogenins: an efficient synthetic strategy and method for related alkaloids
其他题名: 甾体皂甙元E/F环的直接胺化反应: 一个高效合成甾体生物碱的策略和方法
作者: Wu JJ(吴晶晶); Gao R(高冉); Shi Y(史勇); Tian WS(田伟生)
通讯作者: 史勇 ; 田伟生
刊名: Tetrahedron Lett.
发表日期: 2015
DOI: 10.1016/j.tetlet.2015.10.043
卷: 56, 期:47, 页:6639-6642
收录类别: SCI
文章类型: 论文
英文摘要: Herein a direct amination of the EF spiroketal in steroidal sapogenins is reported for the first time. This reaction provides a new strategy and method for the synthesis of steroidal alkaloids, which are generally isolated from Chinese medicinal herbs and pharmaceutically attractive. Solasodine, a steroidal alkaloid with good antitumor bioactivities, is synthesized in three steps and 43% overall yield. (C) 2015 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000364885500026
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39808
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 天然产物有机合成化学重点实验室

Recommended Citation:
Wu JJ,Gao R,Shi Y,et al. Direct amination of EF spiroketal in steroidal sapogenins: an efficient synthetic strategy and method for related alkaloids[J]. Tetrahedron Lett.,2015,56(47):6639-6642.
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