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Direct amination of EF spiroketal in steroidal sapogenins: an efficient synthetic strategy and method for related alkaloids
Alternative Title甾体皂甙元E/F环的直接胺化反应: 一个高效合成甾体生物碱的策略和方法
Wu JJ(吴晶晶); Gao R(高冉); Shi Y(史勇); Tian WS(田伟生)
2015
Source PublicationTetrahedron Lett.
Volume56Issue:47Pages:6639-6642
AbstractHerein a direct amination of the EF spiroketal in steroidal sapogenins is reported for the first time. This reaction provides a new strategy and method for the synthesis of steroidal alkaloids, which are generally isolated from Chinese medicinal herbs and pharmaceutically attractive. Solasodine, a steroidal alkaloid with good antitumor bioactivities, is synthesized in three steps and 43% overall yield. (C) 2015 Elsevier Ltd. All rights reserved.
Subtype论文
Subject Area天然产物有机化学
DOI10.1016/j.tetlet.2015.10.043
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000364885500026
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39808
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorShi Y(史勇); Tian WS(田伟生)
Affiliation中科院上海有机化学研究所, 天然产物有机合成化学重点实验室
Recommended Citation
GB/T 7714
Wu JJ,Gao R,Shi Y,et al. Direct amination of EF spiroketal in steroidal sapogenins: an efficient synthetic strategy and method for related alkaloids[J]. Tetrahedron Lett.,2015,56(47):6639-6642.
APA 吴晶晶,高冉,史勇,&田伟生.(2015).Direct amination of EF spiroketal in steroidal sapogenins: an efficient synthetic strategy and method for related alkaloids.Tetrahedron Lett.,56(47),6639-6642.
MLA 吴晶晶,et al."Direct amination of EF spiroketal in steroidal sapogenins: an efficient synthetic strategy and method for related alkaloids".Tetrahedron Lett. 56.47(2015):6639-6642.
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