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学科主题: 天然产物有机化学
题名: Enantioselective Addition of Heteroarylboronates to Arylimines Catalyzed by a Rhodium-Diene Complex
其他题名: 銠-双烯配体催化的杂环芳基硼酸对芳基亚胺的不对称加成
作者: Chen YJ(陈亚静); Cui Z(崔哲); Feng CG(冯陈国); Lin GQ(林国强)
通讯作者: 冯陈国
刊名: Adv. Synth. Catal.
发表日期: 2015
DOI: 10.1002/adsc.201500147
卷: 357, 期:13, 页:2815-2820
收录类别: SCI
文章类型: 论文
英文摘要: An enantioselective rhodium-catalyzed 1,2-addition of heteroarylboronates to aryl N-tosylimines and N-nosylimines has been developed. Our chiral rhodium-diene catalyst showed high efficiency in the stereochemical control of this reaction. Under the optimal reaction conditions, a variety of boronates bearing pyridinyl, furyl or thienyl groups were successfully reacted with aryl imines. The boronate type, with balance of the stability and reactivity, is critical for achieving high reaction yields in this reaction.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000362527100007
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39806
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 天然产物有机合成化学重点实验室

Recommended Citation:
Chen YJ,Cui Z,Feng CG,et al. Enantioselective Addition of Heteroarylboronates to Arylimines Catalyzed by a Rhodium-Diene Complex[J]. Adv. Synth. Catal.,2015,357(13):2815-2820.
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