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Enantioselective Total Synthesis of (-)-HosieineA
Alternative Title(?)-Hosieine A的对映选择性全合成
Ou YJ(欧阳杰); Yan R(严睿); Mi XW(米贤伟); Hong R(洪然)
Source PublicationAngew. Chem.-Int. Edit.
AbstractThe first total synthesis of (-)-hosieineA was accomplished and features an unprecedented nitroso-ene cyclization to construct the 2-azabicyclo[3.2.1]octane ring system. Phosphine-enabled stereoselective bromohydrination provided interesting mechanistic insights into the anti-Markovnikov process. Also noteworthy is the retention of stereochemistry at C9 in the facile radical debromination initiated by Et3B/air.
Subject Area天然产物有机化学
Indexed BySCI
WOS IDWOS:000360628500044
Citation statistics
Cited Times:17[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorHong R(洪然)
Affiliation中科院上海有机化学研究所, 天然产物有机合成化学重点实验室
Recommended Citation
GB/T 7714
Ou YJ,Yan R,Mi XW,et al. Enantioselective Total Synthesis of (-)-HosieineA[J]. Angew. Chem.-Int. Edit.,2015,54(37):10940-10943.
APA 欧阳杰,严睿,米贤伟,&洪然.(2015).Enantioselective Total Synthesis of (-)-HosieineA.Angew. Chem.-Int. Edit.,54(37),10940-10943.
MLA 欧阳杰,et al."Enantioselective Total Synthesis of (-)-HosieineA".Angew. Chem.-Int. Edit. 54.37(2015):10940-10943.
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