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学科主题: 天然产物有机化学
题名: Enantioselective Total Synthesis of (-)-HosieineA
其他题名: (?)-Hosieine A的对映选择性全合成
作者: Ou YJ(欧阳杰); Yan R(严睿); Mi XW(米贤伟); Hong R(洪然)
通讯作者: 洪然
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201505251
卷: 54, 期:37, 页:10940-10943
收录类别: SCI
文章类型: 论文
英文摘要: The first total synthesis of (-)-hosieineA was accomplished and features an unprecedented nitroso-ene cyclization to construct the 2-azabicyclo[3.2.1]octane ring system. Phosphine-enabled stereoselective bromohydrination provided interesting mechanistic insights into the anti-Markovnikov process. Also noteworthy is the retention of stereochemistry at C9 in the facile radical debromination initiated by Et3B/air.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000360628500044
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39804
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 天然产物有机合成化学重点实验室

Recommended Citation:
Ou YJ,Yan R,Mi XW,et al. Enantioselective Total Synthesis of (-)-HosieineA[J]. Angew. Chem.-Int. Edit.,2015,54(37):10940-10943.
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