| Semisynthesis of Azedarachol from Pregnanetriol, a Degradative Product of Tigogenin | |
| Alternative Title | 从剑麻皂甙元降解的孕甾三醇合成Azedarachol |
| Zhang DS(张东山); Shi Y(史勇); Tian WS(田伟生) | |
| 2015 | |
| Source Publication | Chin. J. Chem.
 |
| Volume | 33Issue:6Pages:669-673 |
| Abstract | We report the first semisynthesis of the natural insect antifeedant azedarachol. The synthesis features the employment of pregnanetriol, a degradative product of the resource natural product tigogenin, as the starting material, the symbiotic reaction involving the mutually-promoting elimination of toluene-sulfonate and deprotection of acetonide, and the controllable reactions between the C16-OH and the C20-OH in pregnane-16,20-diols. |
| Subtype | 论文 |
| Subject Area | 天然产物有机化学 |
| DOI | 10.1002/cjoc.201500231 |
| URL | 查看原文 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000356425200010 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sioc.ac.cn/handle/331003/39798 |
| Collection | 中科院天然产物有机化学重点实验室 |
| Corresponding Author | Shi Y(史勇); Tian WS(田伟生) |
| Affiliation | 中科院上海有机化学研究所, 天然产物有机合成化学重点实验室 |
| Recommended Citation GB/T 7714 | Zhang DS,Shi Y,Tian WS. Semisynthesis of Azedarachol from Pregnanetriol, a Degradative Product of Tigogenin[J]. Chin. J. Chem.,2015,33(6):669-673. |
| APA | 张东山,史勇,&田伟生.(2015).Semisynthesis of Azedarachol from Pregnanetriol, a Degradative Product of Tigogenin.Chin. J. Chem.,33(6),669-673. |
| MLA | 张东山,et al."Semisynthesis of Azedarachol from Pregnanetriol, a Degradative Product of Tigogenin".Chin. J. Chem. 33.6(2015):669-673. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2015353.pdf（391KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | Application Full Text | |
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