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学科主题: 天然产物有机化学
题名: Semisynthesis of Azedarachol from Pregnanetriol, a Degradative Product of Tigogenin
其他题名: 从剑麻皂甙元降解的孕甾三醇合成Azedarachol
作者: Zhang DS(张东山); Shi Y(史勇); Tian WS(田伟生)
通讯作者: 史勇 ; 田伟生
刊名: Chin. J. Chem.
发表日期: 2015
DOI: 10.1002/cjoc.201500231
卷: 33, 期:6, 页:669-673
收录类别: SCI
文章类型: 论文
英文摘要: We report the first semisynthesis of the natural insect antifeedant azedarachol. The synthesis features the employment of pregnanetriol, a degradative product of the resource natural product tigogenin, as the starting material, the symbiotic reaction involving the mutually-promoting elimination of toluene-sulfonate and deprotection of acetonide, and the controllable reactions between the C16-OH and the C20-OH in pregnane-16,20-diols.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000356425200010
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39798
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 天然产物有机合成化学重点实验室

Recommended Citation:
Zhang DS,Shi Y,Tian WS. Semisynthesis of Azedarachol from Pregnanetriol, a Degradative Product of Tigogenin[J]. Chin. J. Chem.,2015,33(6):669-673.
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