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Semisynthesis of Azedarachol from Pregnanetriol, a Degradative Product of Tigogenin
Alternative Title从剑麻皂甙元降解的孕甾三醇合成Azedarachol
Zhang DS(张东山); Shi Y(史勇); Tian WS(田伟生)
2015
Source PublicationChin. J. Chem.
Volume33Issue:6Pages:669-673
AbstractWe report the first semisynthesis of the natural insect antifeedant azedarachol. The synthesis features the employment of pregnanetriol, a degradative product of the resource natural product tigogenin, as the starting material, the symbiotic reaction involving the mutually-promoting elimination of toluene-sulfonate and deprotection of acetonide, and the controllable reactions between the C16-OH and the C20-OH in pregnane-16,20-diols.
Subtype论文
Subject Area天然产物有机化学
DOI10.1002/cjoc.201500231
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000356425200010
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39798
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorShi Y(史勇); Tian WS(田伟生)
Affiliation中科院上海有机化学研究所, 天然产物有机合成化学重点实验室
Recommended Citation
GB/T 7714
Zhang DS,Shi Y,Tian WS. Semisynthesis of Azedarachol from Pregnanetriol, a Degradative Product of Tigogenin[J]. Chin. J. Chem.,2015,33(6):669-673.
APA 张东山,史勇,&田伟生.(2015).Semisynthesis of Azedarachol from Pregnanetriol, a Degradative Product of Tigogenin.Chin. J. Chem.,33(6),669-673.
MLA 张东山,et al."Semisynthesis of Azedarachol from Pregnanetriol, a Degradative Product of Tigogenin".Chin. J. Chem. 33.6(2015):669-673.
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