Synthesis and surface properties study of novel fluorine-containing homopolymer and copolymers for coating applications
其他题名Synthesis and surface properties study of novel fluorine-containing homopolymer and copolymers for coating applications
Sha M(沙敏)1; Zhang D(张丁)1; Pan RM(潘仁明)1; Xing P(邢萍)1; Jiang B(姜标)1
2015
发表期刊Appl. Surf. Sci.
卷号349页码:496-502
摘要A novel fluorochemical methacrylate monomer CH2=C( CH3)CO(O)CH( CF2CF3)( CF( CF3)(2)) (2) containing short branched fluoroaliphatic groups is synthesized successfully from perfluoro ethyl isopropyl ketone. The homopolymer of 2 and copolymers of 2 and butyl methacrylate (BMA) with different fluorine contents are prepared. All the polymers have good thermal stability. A series of solutions of 3 wt% polymer in CCl2FCClF2 (R-113) are applied to clean coverslips. Properties of fluorinated polymer films are investigated. The results demonstrate that the homopolymer had excellent repellency properties which are slightly worse than that of polymers containing primarily straight-chain perfluorooctyl moieties but are better than that of polymers containing primarily straight-chain perfluorohexyl moieties. The water repellency decreases significantly when the fluorine content is less than 10% while the oil repellency decreases significantly when the fluorine content is less than 15%, thereby introducing BMA to copolymerize with 2 is a perfect method based on cost, solubility and performance standpoints. (C) 2015 Elsevier B.V. All rights reserved.
文章类型论文
学科领域天然产物有机化学
DOI10.1016/j.apsusc.2015.04.219
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000357129100067
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/39792
专题中科院天然产物有机化学重点实验室
通讯作者Jiang B(姜标)
作者单位1.中科院上海有机化学研究所, 天然产物有机合成化学重点实验室
2.南京理工大学
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Sha M,Zhang D,Pan RM,et al. Synthesis and surface properties study of novel fluorine-containing homopolymer and copolymers for coating applications[J]. Appl. Surf. Sci.,2015,349:496-502.
APA 沙敏,张丁,潘仁明,邢萍,&姜标.(2015).Synthesis and surface properties study of novel fluorine-containing homopolymer and copolymers for coating applications.Appl. Surf. Sci.,349,496-502.
MLA 沙敏,et al."Synthesis and surface properties study of novel fluorine-containing homopolymer and copolymers for coating applications".Appl. Surf. Sci. 349(2015):496-502.
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