SIOC OpenIR  > 中科院天然产物有机化学重点实验室
Synthesis and surface properties study of novel fluorine-containing homopolymer and copolymers for coating applications
Alternative TitleSynthesis and surface properties study of novel fluorine-containing homopolymer and copolymers for coating applications
Sha M(沙敏)1; Zhang D(张丁)1; Pan RM(潘仁明)1; Xing P(邢萍)1; Jiang B(姜标)1
2015
Source PublicationAppl. Surf. Sci.
Volume349Pages:496-502
AbstractA novel fluorochemical methacrylate monomer CH2=C( CH3)CO(O)CH( CF2CF3)( CF( CF3)(2)) (2) containing short branched fluoroaliphatic groups is synthesized successfully from perfluoro ethyl isopropyl ketone. The homopolymer of 2 and copolymers of 2 and butyl methacrylate (BMA) with different fluorine contents are prepared. All the polymers have good thermal stability. A series of solutions of 3 wt% polymer in CCl2FCClF2 (R-113) are applied to clean coverslips. Properties of fluorinated polymer films are investigated. The results demonstrate that the homopolymer had excellent repellency properties which are slightly worse than that of polymers containing primarily straight-chain perfluorooctyl moieties but are better than that of polymers containing primarily straight-chain perfluorohexyl moieties. The water repellency decreases significantly when the fluorine content is less than 10% while the oil repellency decreases significantly when the fluorine content is less than 15%, thereby introducing BMA to copolymerize with 2 is a perfect method based on cost, solubility and performance standpoints. (C) 2015 Elsevier B.V. All rights reserved.
Subtype论文
Subject Area天然产物有机化学
DOI10.1016/j.apsusc.2015.04.219
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000357129100067
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39792
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorJiang B(姜标)
Affiliation1.中科院上海有机化学研究所, 天然产物有机合成化学重点实验室
2.南京理工大学
Recommended Citation
GB/T 7714
Sha M,Zhang D,Pan RM,et al. Synthesis and surface properties study of novel fluorine-containing homopolymer and copolymers for coating applications[J]. Appl. Surf. Sci.,2015,349:496-502.
APA 沙敏,张丁,潘仁明,邢萍,&姜标.(2015).Synthesis and surface properties study of novel fluorine-containing homopolymer and copolymers for coating applications.Appl. Surf. Sci.,349,496-502.
MLA 沙敏,et al."Synthesis and surface properties study of novel fluorine-containing homopolymer and copolymers for coating applications".Appl. Surf. Sci. 349(2015):496-502.
Files in This Item:
File Name/Size DocType Version Access License
2015328.pdf(1208KB)期刊论文作者接受稿开放获取CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[沙敏]'s Articles
[张丁]'s Articles
[潘仁明]'s Articles
Baidu academic
Similar articles in Baidu academic
[沙敏]'s Articles
[张丁]'s Articles
[潘仁明]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[沙敏]'s Articles
[张丁]'s Articles
[潘仁明]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.