SIOC OpenIR  > 中科院天然产物有机化学重点实验室
Concise Synthesis of the Core Structures of Saundersiosides
Alternative TitleSaundersiosides母核结构单元的简洁合成
Cheng SL(程寿玲); Jiang XL(蒋小玲); Shi Y(史勇); Tian WS(田伟生)
2015
Source PublicationOrg. Lett.
Volume17Issue:10Pages:2346-2349
AbstractA divergent synthesis of three core pentacyclic lactones of nine rearranged cholestane sapogenins, saundersiosides A-H (1-8) and candicanoside A (9), is reported. Key features include a one-flask CBS reduction/Brown hydroboration-oxidation, a SmI2-mediated intramolecular Reformatskii reaction, and an intramolecular transesterification. This synthesis provides a general strategy and key precursors for the collective synthesis of natural and designed saundersiosides. An efficient formal synthesis of candicanoside A is also achieved.
Subtype论文
Subject Area天然产物有机化学
DOI10.1021/acs.orglett.5b00821
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000354908300014
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39786
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorShi Y(史勇); Tian WS(田伟生)
Affiliation中科院上海有机化学研究所, 天然产物有机合成化学重点实验室
Recommended Citation
GB/T 7714
Cheng SL,Jiang XL,Shi Y,et al. Concise Synthesis of the Core Structures of Saundersiosides[J]. Org. Lett.,2015,17(10):2346-2349.
APA 程寿玲,蒋小玲,史勇,&田伟生.(2015).Concise Synthesis of the Core Structures of Saundersiosides.Org. Lett.,17(10),2346-2349.
MLA 程寿玲,et al."Concise Synthesis of the Core Structures of Saundersiosides".Org. Lett. 17.10(2015):2346-2349.
Files in This Item:
File Name/Size DocType Version Access License
2015279.pdf(1173KB)期刊论文作者接受稿开放获取CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[程寿玲]'s Articles
[蒋小玲]'s Articles
[史勇]'s Articles
Baidu academic
Similar articles in Baidu academic
[程寿玲]'s Articles
[蒋小玲]'s Articles
[史勇]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[程寿玲]'s Articles
[蒋小玲]'s Articles
[史勇]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.