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[2.2]Paracyclophane-Derived Monodentate Phosphoramidite Ligands for Copper-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Substituted Chalcones
Alternative Title[2.2]Paracyclophane-Derived Monodentate Phosphoramidite Ligands for Copper-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Substituted Chalcones
Han L(韩磊)1; Lei Y(雷洋)1; Xing P(邢萍)1; Zhao XL(赵小龙)1; Jiang B(姜标)1
2015
Source PublicationJ. Org. Chem.
Volume80Issue:8Pages:3752-3757
AbstractCopper-catalyzed asymmetric conjugate addition of diethylzinc to chalcones could be realized by using [2.2]paracyclophane-derived monodentate phosphoramidite ligands. The excellent yield and enantioselectivity (up to 98% yield and 95% enantiomeric excess) could be realized with low catalyst loading of 1.0 mol % and low ligand loading of 1.2%.
Subtype论文
Subject Area天然产物有机化学
DOI10.1021/jo502715f
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000353315000003
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39783
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorJiang B(姜标)
Affiliation1.中科院上海有机化学研究所, 天然产物有机合成化学重点实验室
2.中科院上海高等研究院
Recommended Citation
GB/T 7714
Han L,Lei Y,Xing P,et al. [2.2]Paracyclophane-Derived Monodentate Phosphoramidite Ligands for Copper-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Substituted Chalcones[J]. J. Org. Chem.,2015,80(8):3752-3757.
APA 韩磊,雷洋,邢萍,赵小龙,&姜标.(2015).[2.2]Paracyclophane-Derived Monodentate Phosphoramidite Ligands for Copper-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Substituted Chalcones.J. Org. Chem.,80(8),3752-3757.
MLA 韩磊,et al."[2.2]Paracyclophane-Derived Monodentate Phosphoramidite Ligands for Copper-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Substituted Chalcones".J. Org. Chem. 80.8(2015):3752-3757.
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