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学科主题: 天然产物有机化学
题名: [2.2]Paracyclophane-Derived Monodentate Phosphoramidite Ligands for Copper-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Substituted Chalcones
其他题名: [2.2]Paracyclophane-Derived Monodentate Phosphoramidite Ligands for Copper-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Substituted Chalcones
作者: Han L(韩磊)1; Lei Y(雷洋)1; Xing P(邢萍)1; Zhao XL(赵小龙)1; Jiang B(姜标)1
通讯作者: 姜标
刊名: J. Org. Chem.
发表日期: 2015
DOI: 10.1021/jo502715f
卷: 80, 期:8, 页:3752-3757
收录类别: SCI
文章类型: 论文
英文摘要: Copper-catalyzed asymmetric conjugate addition of diethylzinc to chalcones could be realized by using [2.2]paracyclophane-derived monodentate phosphoramidite ligands. The excellent yield and enantioselectivity (up to 98% yield and 95% enantiomeric excess) could be realized with low catalyst loading of 1.0 mol % and low ligand loading of 1.2%.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000353315000003
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39783
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 天然产物有机合成化学重点实验室
2.中科院上海高等研究院

Recommended Citation:
Han L,Lei Y,Xing P,et al. [2.2]Paracyclophane-Derived Monodentate Phosphoramidite Ligands for Copper-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Substituted Chalcones[J]. J. Org. Chem.,2015,80(8):3752-3757.
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