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学科主题: 天然产物有机化学
题名: Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity
其他题名: 铜催化的手性叔丁基亚磺酰胺的不对称烯丙基化: 双立体控制下的绝对非对映选择性
作者: Zhao YS(赵一爽)1; Liu Q(刘强)1; Tian P(田平)1; TAO JINGCHAO1; Lin GQ(林国强)1
通讯作者: 田平 ; TAO JINGCHAO
刊名: Org. Biomol. Chem.
发表日期: 2015
DOI: 10.1039/c5ob00322a
卷: 13, 期:14, 页:4174-4178
收录类别: SCI
文章类型: 论文
英文摘要: Copper-catalyzed asymmetric allylation of chiral N-tert-butane-sulfinyl imines has been described. Dual stereocontrol, through the combination of a chiral auxiliary and a chiral copper complex, has played an important role in achieving the nearly perfect diastereo-selectivities (all dr > 99 : 1), especially for ketimine substrates.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000351618000008
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39782
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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作者单位: 1.郑州大学
2.中科院上海有机化学研究所, 天然产物有机合成化学重点实验室

Recommended Citation:
Zhao YS,Liu Q,Tian P,et al. Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity[J]. Org. Biomol. Chem.,2015,13(14):4174-4178.
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