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Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity
Alternative Title铜催化的手性叔丁基亚磺酰胺的不对称烯丙基化: 双立体控制下的绝对非对映选择性
Zhao YS(赵一爽)1; Liu Q(刘强)1; Tian P(田平)1; TAO JINGCHAO1; Lin GQ(林国强)1
2015
Source PublicationOrg. Biomol. Chem.
Volume13Issue:14Pages:4174-4178
AbstractCopper-catalyzed asymmetric allylation of chiral N-tert-butane-sulfinyl imines has been described. Dual stereocontrol, through the combination of a chiral auxiliary and a chiral copper complex, has played an important role in achieving the nearly perfect diastereo-selectivities (all dr > 99 : 1), especially for ketimine substrates.
Subtype论文
Subject Area天然产物有机化学
DOI10.1039/c5ob00322a
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000351618000008
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39782
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorTian P(田平); TAO JINGCHAO
Affiliation1.郑州大学
2.中科院上海有机化学研究所, 天然产物有机合成化学重点实验室
Recommended Citation
GB/T 7714
Zhao YS,Liu Q,Tian P,et al. Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity[J]. Org. Biomol. Chem.,2015,13(14):4174-4178.
APA 赵一爽,刘强,田平,TAO JINGCHAO,&林国强.(2015).Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity.Org. Biomol. Chem.,13(14),4174-4178.
MLA 赵一爽,et al."Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity".Org. Biomol. Chem. 13.14(2015):4174-4178.
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