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学科主题: 天然产物有机化学
题名: Facile synthesis of solasodine based on a mild halogenation-ring opening reaction of spiroketals in steroidal sapogenins
其他题名: 基于甾体皂甙元卤代开环反应合成solasodine
作者: Wu JJ(吴晶晶); Shi Y(史勇); Tian WS(田伟生)
通讯作者: 史勇 ; 田伟生
刊名: Tetrahedron Lett.
发表日期: 2015
DOI: 10.1016/j.tetlet.2015.01.149
卷: 56, 期:10, 页:1215-1217
收录类别: SCI
文章类型: 论文
英文摘要: Herein we report a halogenation-ring opening reaction of spiroketals in steroidal sapogenins at room temperature to gain highly valuable omega-halo enol ethers in excellent yields. Boosted by this method, we have prepared solasodine, an antitumor steroidal alkaloid, from diosgenin acetate in three steps with an overall yield of 50%. (C) 2015 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000350528300011
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39780
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 天然产物有机合成化学重点实验室

Recommended Citation:
Wu JJ,Shi Y,Tian WS. Facile synthesis of solasodine based on a mild halogenation-ring opening reaction of spiroketals in steroidal sapogenins[J]. Tetrahedron Lett.,2015,56(10):1215-1217.
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