Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids
其他题名Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids
Zhu LL(朱莉莉)1; Huang SH(黄莎华)1; Yu J(于静)1; Hong R(洪然)1
2015
发表期刊Tetrahedron Lett.
卷号56期号:1页码:23-31
摘要In this Digest, innovative strategies and tactics attributed to construct a full 6–6-fused bicyclo[3.2.1]octane framework of ent-kauranoids are highlighted. Although the first synthesis of ent-kaurene was reported fifty years ago, modern synthetic methods continue to sustain this field to the frontier of synthetic chemistry. Recent advances implemented new perspectives in the construction of bicycle[3.2.1]octane skeleton as well as the overall efficiency of synthesis. Biogenesis of ent-kaurene was recently revisited by comprehensive computational analysis. An updated proposal argued that ent-beyerane is derived from ent-kauranyl cation since the secondary carbocation is energetically unfavorable, which may throw light on new experimental design and further biomimicry study to better understand the origin of this vast category of ent-kauranoids.
文章类型论文
学科领域天然产物有机化学
DOI10.1016/j.tetlet.2014.11.035
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000348259800002
引用统计
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/39778
专题中科院天然产物有机化学重点实验室
通讯作者Zhu LL(朱莉莉); Hong R(洪然)
作者单位1.中科院上海有机化学研究所
2.上海应用技术学院
推荐引用方式
GB/T 7714
Zhu LL,Huang SH,Yu J,et al. Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids[J]. Tetrahedron Lett.,2015,56(1):23-31.
APA 朱莉莉,黄莎华,于静,&洪然.(2015).Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids.Tetrahedron Lett.,56(1),23-31.
MLA 朱莉莉,et al."Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids".Tetrahedron Lett. 56.1(2015):23-31.
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