SIOC OpenIR  > 中科院天然产物有机化学重点实验室
Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids
Alternative TitleConstructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids
Zhu LL(朱莉莉)1; Huang SH(黄莎华)1; Yu J(于静)1; Hong R(洪然)1
2015
Source PublicationTetrahedron Lett.
Volume56Issue:1Pages:23-31
AbstractIn this Digest, innovative strategies and tactics attributed to construct a full 6–6-fused bicyclo[3.2.1]octane framework of ent-kauranoids are highlighted. Although the first synthesis of ent-kaurene was reported fifty years ago, modern synthetic methods continue to sustain this field to the frontier of synthetic chemistry. Recent advances implemented new perspectives in the construction of bicycle[3.2.1]octane skeleton as well as the overall efficiency of synthesis. Biogenesis of ent-kaurene was recently revisited by comprehensive computational analysis. An updated proposal argued that ent-beyerane is derived from ent-kauranyl cation since the secondary carbocation is energetically unfavorable, which may throw light on new experimental design and further biomimicry study to better understand the origin of this vast category of ent-kauranoids.
Subtype论文
Subject Area天然产物有机化学
DOI10.1016/j.tetlet.2014.11.035
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000348259800002
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39778
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorZhu LL(朱莉莉); Hong R(洪然)
Affiliation1.中科院上海有机化学研究所
2.上海应用技术学院
Recommended Citation
GB/T 7714
Zhu LL,Huang SH,Yu J,et al. Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids[J]. Tetrahedron Lett.,2015,56(1):23-31.
APA 朱莉莉,黄莎华,于静,&洪然.(2015).Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids.Tetrahedron Lett.,56(1),23-31.
MLA 朱莉莉,et al."Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids".Tetrahedron Lett. 56.1(2015):23-31.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[朱莉莉]'s Articles
[黄莎华]'s Articles
[于静]'s Articles
Baidu academic
Similar articles in Baidu academic
[朱莉莉]'s Articles
[黄莎华]'s Articles
[于静]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[朱莉莉]'s Articles
[黄莎华]'s Articles
[于静]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.