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学科主题: 天然产物有机化学
题名: Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids
其他题名: Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids
作者: Zhu LL(朱莉莉)1; Huang SH(黄莎华)1; Yu J(于静)1; Hong R(洪然)1
通讯作者: 朱莉莉 ; 洪然
刊名: Tetrahedron Lett.
发表日期: 2015
DOI: 10.1016/j.tetlet.2014.11.035
卷: 56, 期:1, 页:23-31
收录类别: SCI
文章类型: 论文
英文摘要: In this Digest, innovative strategies and tactics attributed to construct a full 6–6-fused bicyclo[3.2.1]octane framework of ent-kauranoids are highlighted. Although the first synthesis of ent-kaurene was reported fifty years ago, modern synthetic methods continue to sustain this field to the frontier of synthetic chemistry. Recent advances implemented new perspectives in the construction of bicycle[3.2.1]octane skeleton as well as the overall efficiency of synthesis. Biogenesis of ent-kaurene was recently revisited by comprehensive computational analysis. An updated proposal argued that ent-beyerane is derived from ent-kauranyl cation since the secondary carbocation is energetically unfavorable, which may throw light on new experimental design and further biomimicry study to better understand the origin of this vast category of ent-kauranoids.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000348259800002
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39778
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所
2.上海应用技术学院

Recommended Citation:
Zhu LL,Huang SH,Yu J,et al. Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids[J]. Tetrahedron Lett.,2015,56(1):23-31.
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