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Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids
Alternative TitleConstructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids
Zhu LL(朱莉莉)1; Huang SH(黄莎华)1; Yu J(于静)1; Hong R(洪然)1
Source PublicationTetrahedron Lett.
AbstractIn this Digest, innovative strategies and tactics attributed to construct a full 6–6-fused bicyclo[3.2.1]octane framework of ent-kauranoids are highlighted. Although the first synthesis of ent-kaurene was reported fifty years ago, modern synthetic methods continue to sustain this field to the frontier of synthetic chemistry. Recent advances implemented new perspectives in the construction of bicycle[3.2.1]octane skeleton as well as the overall efficiency of synthesis. Biogenesis of ent-kaurene was recently revisited by comprehensive computational analysis. An updated proposal argued that ent-beyerane is derived from ent-kauranyl cation since the secondary carbocation is energetically unfavorable, which may throw light on new experimental design and further biomimicry study to better understand the origin of this vast category of ent-kauranoids.
Subject Area天然产物有机化学
Indexed BySCI
WOS IDWOS:000348259800002
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Document Type期刊论文
Corresponding AuthorZhu LL(朱莉莉); Hong R(洪然)
Recommended Citation
GB/T 7714
Zhu LL,Huang SH,Yu J,et al. Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids[J]. Tetrahedron Lett.,2015,56(1):23-31.
APA 朱莉莉,黄莎华,于静,&洪然.(2015).Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids.Tetrahedron Lett.,56(1),23-31.
MLA 朱莉莉,et al."Constructive Innovation of Approaching Bicyclo[3.2.1]octane in ent-Kauranoids".Tetrahedron Lett. 56.1(2015):23-31.
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