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学科主题: 氟化学
题名: Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins
其他题名: 二氟卡宾与重氮卡宾的交叉偶联
作者: Zheng J(郑剑)1; Lin JH(林锦鸿)1; Yu LY(余柳英)1; Wei Y(魏云)1; Zheng X(郑兴)1; Xiao JC(肖吉昌)1
通讯作者: 肖吉昌
刊名: Org. Lett.
发表日期: 2015
DOI: 10.1021/acs.orglett.5b03159
卷: 17, 期:24, 页:6150-6153
收录类别: SCI
文章类型: 论文
英文摘要: Cross-coupling between difluorocarbene and carbene-derived intermediates generated from diazocompounds was developed to give gem-difluoroolefins, which constitutes a fast practical pathway to achieve hindered gem-difluoroolefins. The cross-coupling between difluorocarbene and aryl diazoacetates proceeded smoothly in the presence of a copper source, whereas its coupling with diaryl diazomethanes occurred well under metal-free conditions. A mechanism involving a copperdifluorocarbene complex was proposed
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000366878300054
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39769
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.南华大学

Recommended Citation:
Zheng J,Lin JH,Yu LY,et al. Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins[J]. Org. Lett.,2015,17(24):6150-6153.
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