SIOC OpenIR  > 中科院有机氟化学重点实验室
Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins
Alternative Title二氟卡宾与重氮卡宾的交叉偶联
Zheng J(郑剑)1; Lin JH(林锦鸿)1; Yu LY(余柳英)1; Wei Y(魏云)1; Zheng X(郑兴)1; Xiao JC(肖吉昌)1
2015
Source PublicationOrg. Lett.
Volume17Issue:24Pages:6150-6153
AbstractCross-coupling between difluorocarbene and carbene-derived intermediates generated from diazocompounds was developed to give gem-difluoroolefins, which constitutes a fast practical pathway to achieve hindered gem-difluoroolefins. The cross-coupling between difluorocarbene and aryl diazoacetates proceeded smoothly in the presence of a copper source, whereas its coupling with diaryl diazomethanes occurred well under metal-free conditions. A mechanism involving a copperdifluorocarbene complex was proposed
Subtype论文
Subject Area氟化学
DOI10.1021/acs.orglett.5b03159
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000366878300054
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39769
Collection中科院有机氟化学重点实验室
Corresponding AuthorXiao JC(肖吉昌)
Affiliation1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.南华大学
Recommended Citation
GB/T 7714
Zheng J,Lin JH,Yu LY,et al. Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins[J]. Org. Lett.,2015,17(24):6150-6153.
APA 郑剑,林锦鸿,余柳英,魏云,郑兴,&肖吉昌.(2015).Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins.Org. Lett.,17(24),6150-6153.
MLA 郑剑,et al."Cross-Coupling between Difluorocarbene and Carbene-Derived Intermediates Generated from Diazocompounds for the Synthesis of gem-Difluoroolefins".Org. Lett. 17.24(2015):6150-6153.
Files in This Item:
File Name/Size DocType Version Access License
2015684.pdf(616KB)期刊论文作者接受稿开放获取CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[郑剑]'s Articles
[林锦鸿]'s Articles
[余柳英]'s Articles
Baidu academic
Similar articles in Baidu academic
[郑剑]'s Articles
[林锦鸿]'s Articles
[余柳英]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[郑剑]'s Articles
[林锦鸿]'s Articles
[余柳英]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.