SIOC OpenIR  > 中科院有机氟化学重点实验室
Visible-Light-Induced Photocatalysis of 1,1,1-Trifluoro-2-iodoethane with Alkylalkenes and Silyl Enol Ethers
Alternative Title可见光促进的烯烃和烯醇硅醚与三氟碘乙烷的三氟乙基化反应
Huang MW(黄美薇)1; Li L(李伦)1; Zhao ZG(赵志刚)1; Chen QY(陈庆云)1; Guo Y(郭勇)1
2015
Source PublicationSynthesis
Volume47Issue:24Pages:3891-3900
AbstractReactions of 1,1,1-trifluoro-2-iodoethane with alkylalkenes and silyl enol ethers were performed in the presence of a catalytic amount of fac-Ir(ppy)(3) and an excessive amount of Hunig's base in acetonitrile irradiated by a 24 W fluorescent lamp under nitrogen atmosphere for 48 hours. The visible-light-induced photoredox reactions introduce simultaneously a 2,2,2-trifluoroethyl group and an iodine atom to both sides of the double bond of ordinary alkenes via an atom-transfer radical addition (ATRA). The same reaction with silyl enol ethers generates -trifluoromethyl ketones, which are typically a challenge to synthesize. The reactions proved to be tolerant of a variety of functionalities.
Subtype论文
Subject Area氟化学
DOI10.1055/s-0035-1560260
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000366209800008
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39765
Collection中科院有机氟化学重点实验室
Corresponding AuthorZhao ZG(赵志刚); Chen QY(陈庆云); Guo Y(郭勇)
Affiliation1.西南民族大学
2.中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Huang MW,Li L,Zhao ZG,et al. Visible-Light-Induced Photocatalysis of 1,1,1-Trifluoro-2-iodoethane with Alkylalkenes and Silyl Enol Ethers[J]. Synthesis,2015,47(24):3891-3900.
APA 黄美薇,李伦,赵志刚,陈庆云,&郭勇.(2015).Visible-Light-Induced Photocatalysis of 1,1,1-Trifluoro-2-iodoethane with Alkylalkenes and Silyl Enol Ethers.Synthesis,47(24),3891-3900.
MLA 黄美薇,et al."Visible-Light-Induced Photocatalysis of 1,1,1-Trifluoro-2-iodoethane with Alkylalkenes and Silyl Enol Ethers".Synthesis 47.24(2015):3891-3900.
Files in This Item:
File Name/Size DocType Version Access License
2015659.pdf(917KB)期刊论文作者接受稿开放获取CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[黄美薇]'s Articles
[李伦]'s Articles
[赵志刚]'s Articles
Baidu academic
Similar articles in Baidu academic
[黄美薇]'s Articles
[李伦]'s Articles
[赵志刚]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[黄美薇]'s Articles
[李伦]'s Articles
[赵志刚]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.