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学科主题: 氟化学
题名: Nickel-Catalyzed Reductive Cross-Coupling of (Hetero)Aryl Iodides with Fluorinated Secondary Alkyl Bromides
其他题名: 镍催化下(杂)芳基碘代物与氟代二级溴代烷烃的还原偶联反应
作者: Li XF(李学飞)1; Feng Z(冯璋)1; Jiang ZX(江中兴)1; Zhang XG(张新刚)1
通讯作者: 江中兴 ; 张新刚
刊名: Org. Lett.
发表日期: 2015
DOI: 10.1021/acs.orglett.5b02716
卷: 17, 期:22, 页:5570-5573
收录类别: SCI
文章类型: 论文
英文摘要: A mild and efficient nickel-catalyzed reductive cross-coupling between fluorinated secondary alkyl bromides and (hetero)aryl iodides is described. The use of FeBr2 as an additive successfully overcomes the hydrodebromination and beta-fluorine elimination of fluorinated substrates and allows the efficient synthesis of a wide range of trifluoromethyl and difluoroalkyl containing aliphatic compounds with a fluoroalkyl substituted tertiary carbon center. The notable features of this protocol are the synthetic and operational simplicity without preparation of moisture sensitive organometallic reagents and excellent functional group compatibility, even toward active proton containing substrates.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000365462900015
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39763
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.武汉大学
2.中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Li XF,Feng Z,Jiang ZX,et al. Nickel-Catalyzed Reductive Cross-Coupling of (Hetero)Aryl Iodides with Fluorinated Secondary Alkyl Bromides[J]. Org. Lett.,2015,17(22):5570-5573.
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