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Review of recent advances in C-F bond activation of aliphatic fluorides
Alternative Title烷基氟化物碳氟键断裂的进展综述
Shen Q(沈倩)1; Huang YG(黄焰根)1; Liu C(刘超)1; Xiao JC(肖吉昌)1; Chen QY(陈庆云)1; Guo Y(郭勇)1
Source PublicationJ. Fluor. Chem.
AbstractC-F bond activation of aliphatic fluorides provides new methodologies for synthesis of new fluorinated building blocks as well as versatile non-fluorinated products. This review covers the recent C-F bond cleavage examples and further transformation of compounds bearing with an aliphatic fluoride, difluoromethylene group or trifluoromethyl groups. The methods to activate a C-F bond include activation by Lewis acid, Bronsted superacids and hydrogen bonding, and mediation by transition-metals and rare earth metals. Partial reduction of trifluoromethyl group through a single electron transfer (SET) process can provide the compounds with less fluorine. Bases are often used for the elimination of hydrofluoride. S(N)2' displacement is also an important method for transformation of monofluorinated, difluorinated and trifluorinated olefins to various synthetically interesting molecules. (C) 2015 Elsevier B.V. All rights reserved.
Subject Area氟化学
Indexed BySCI
WOS IDWOS:000364881000003
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Document Type期刊论文
Corresponding AuthorHuang YG(黄焰根); Chen QY(陈庆云); Guo Y(郭勇)
2.中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Shen Q,Huang YG,Liu C,et al. Review of recent advances in C-F bond activation of aliphatic fluorides[J]. J. Fluor. Chem.,2015,179:14-22.
APA 沈倩,黄焰根,刘超,肖吉昌,陈庆云,&郭勇.(2015).Review of recent advances in C-F bond activation of aliphatic fluorides.J. Fluor. Chem.,179,14-22.
MLA 沈倩,et al."Review of recent advances in C-F bond activation of aliphatic fluorides".J. Fluor. Chem. 179(2015):14-22.
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