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学科主题: 氟化学
题名: Review of recent advances in C-F bond activation of aliphatic fluorides
其他题名: 烷基氟化物碳氟键断裂的进展综述
作者: Shen Q(沈倩)1; Huang YG(黄焰根)1; Liu C(刘超)1; Xiao JC(肖吉昌)1; Chen QY(陈庆云)1; Guo Y(郭勇)1
通讯作者: 黄焰根 ; 陈庆云 ; 郭勇
刊名: J. Fluor. Chem.
发表日期: 2015
DOI: 10.1016/j.jfluchem.2015.07.007
卷: 179, 页:14-22
收录类别: SCI
文章类型: 论文
英文摘要: C-F bond activation of aliphatic fluorides provides new methodologies for synthesis of new fluorinated building blocks as well as versatile non-fluorinated products. This review covers the recent C-F bond cleavage examples and further transformation of compounds bearing with an aliphatic fluoride, difluoromethylene group or trifluoromethyl groups. The methods to activate a C-F bond include activation by Lewis acid, Bronsted superacids and hydrogen bonding, and mediation by transition-metals and rare earth metals. Partial reduction of trifluoromethyl group through a single electron transfer (SET) process can provide the compounds with less fluorine. Bases are often used for the elimination of hydrofluoride. S(N)2' displacement is also an important method for transformation of monofluorinated, difluorinated and trifluorinated olefins to various synthetically interesting molecules. (C) 2015 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000364881000003
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39761
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.东华大学
2.中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Shen Q,Huang YG,Liu C,et al. Review of recent advances in C-F bond activation of aliphatic fluorides[J]. J. Fluor. Chem.,2015,179:14-22.
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