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学科主题: 氟化学
题名: Chemically oxidative fluorination with fluoride ions
其他题名: 以氟负离子进行的化学氧化氟化
作者: Ni CF(倪传法); Jiang FZ(姜範洲); Ceng YW(曾裕文); Hu JB(胡金波)
通讯作者: 胡金波
刊名: J. Fluor. Chem.
发表日期: 2015
DOI: 10.1016/j.jfluchem.2015.06.026
卷: 179, 页:3-13
收录类别: SCI
文章类型: 论文
英文摘要: Although the chemical oxidation of fluoride ions is generally challenging due to the high electronegativity of fluorine, in the past four years, a number of oxidative fluorination reactions via the reactivity umpolung of substrates or fluorides have been developed. These reactions can introduce fluorine into nucleophilic or electron-neutral systems. This short review provides a summary on the recent developments of oxidative fluorination of arenes, alkanes, and alkenes with fluorides promoted by various oxidants. These newly developed reactions are of high selectivity and efficiency, and provide a pathway for the more efficient use of the abundant, yet less nucleophilic fluorides. (C) 2015 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000364881000002
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39760
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Ni CF,Jiang FZ,Ceng YW,et al. Chemically oxidative fluorination with fluoride ions[J]. J. Fluor. Chem.,2015,179:3-13.
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