SIOC OpenIR  > 中科院有机氟化学重点实验室
Chemically oxidative fluorination with fluoride ions
Alternative Title以氟负离子进行的化学氧化氟化
Ni CF(倪传法); Jiang FZ(姜範洲); Ceng YW(曾裕文); Hu JB(胡金波)
Source PublicationJ. Fluor. Chem.
AbstractAlthough the chemical oxidation of fluoride ions is generally challenging due to the high electronegativity of fluorine, in the past four years, a number of oxidative fluorination reactions via the reactivity umpolung of substrates or fluorides have been developed. These reactions can introduce fluorine into nucleophilic or electron-neutral systems. This short review provides a summary on the recent developments of oxidative fluorination of arenes, alkanes, and alkenes with fluorides promoted by various oxidants. These newly developed reactions are of high selectivity and efficiency, and provide a pathway for the more efficient use of the abundant, yet less nucleophilic fluorides. (C) 2015 Elsevier B.V. All rights reserved.
Subject Area氟化学
Indexed BySCI
WOS IDWOS:000364881000002
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Document Type期刊论文
Corresponding AuthorHu JB(胡金波)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Ni CF,Jiang FZ,Ceng YW,et al. Chemically oxidative fluorination with fluoride ions[J]. J. Fluor. Chem.,2015,179:3-13.
APA 倪传法,姜範洲,曾裕文,&胡金波.(2015).Chemically oxidative fluorination with fluoride ions.J. Fluor. Chem.,179,3-13.
MLA 倪传法,et al."Chemically oxidative fluorination with fluoride ions".J. Fluor. Chem. 179(2015):3-13.
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