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学科主题: 氟化学
题名: Cu-Mediated 2,2,2-trifluoroethylation of terminal alkynes using 1,1-dichloro-2,2,2-trifluoroethane (HCFC-123)
其他题名: 用1,1-二氯-2,2,2-三氟乙烷(HCFC-123)的铜促-2,2,2-三氟乙基化反应
作者: Han EJ(韩恩健)1; Sun Y(孙岩)1; Shen Q(沈倩)1; Chen QY(陈庆云)1; Guo Y(郭勇)1; Huang YG(黄焰根)1
通讯作者: 陈庆云 ; 郭勇
刊名: Org. Chem. Front.
发表日期: 2015
DOI: 10.1039/c5qo00210a
卷: 2, 期:10, 页:1379-1387
收录类别: SCI
文章类型: 论文
英文摘要: The title reaction provides a novel utilization of ozone-depleting/global-warming HCFCs as a new carbon-carbon cross-coupling model of various terminal alkynes by activating two inert C-Cl bonds successively. This protocol provided trifluoroethylated alkynes efficiently under mild reaction conditions and was compatible with a broad range of functional groups. An example of the synthesis of a terbinafine analogue is shown. Some mechanistic experiments including deuterated reagents and radical/SET inhibitors are described.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000364450000015
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39759
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.东华大学

Recommended Citation:
Han EJ,Sun Y,Shen Q,et al. Cu-Mediated 2,2,2-trifluoroethylation of terminal alkynes using 1,1-dichloro-2,2,2-trifluoroethane (HCFC-123)[J]. Org. Chem. Front.,2015,2(10):1379-1387.
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