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Copper-catalyzed stereoselective oxytrifluoro-methylation of propargyl amides for the construction of oxazolines
Alternative Title可构建噁唑啉环的铜催化的N-炔丙基酰胺的立体选择性oxytrifluoromethylation反应
Wang YN(王亚南); Jiang M(蒋敏); Liu JT(刘金涛)
2015
Source PublicationOrg. Chem. Front.
Volume2Issue:5Pages:542-547
AbstractThe copper-catalyzed stereoselective oxytrifluoromethylation of terminal propargyl amides took place readily in the presence of Togni's reagent under mild conditions, giving the corresponding trifluoro-methylated oxazoline derivatives in moderate to good yields. Using CuBr as catalyst, the E-isomer was obtained as major product. However, the formation of Z-isomer with excellent stereoselectivity was also achieved while Cu(CH3CN)(4)PF6 was used. Plausible pathways are proposed to account for the excellent stereoselectivity of the reaction.
Subtype论文
Subject Area氟化学
DOI10.1039/c5qo00044k
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000364445300016
Citation statistics
Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39757
Collection中科院有机氟化学重点实验室
Corresponding AuthorLiu JT(刘金涛)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Wang YN,Jiang M,Liu JT. Copper-catalyzed stereoselective oxytrifluoro-methylation of propargyl amides for the construction of oxazolines[J]. Org. Chem. Front.,2015,2(5):542-547.
APA 王亚南,蒋敏,&刘金涛.(2015).Copper-catalyzed stereoselective oxytrifluoro-methylation of propargyl amides for the construction of oxazolines.Org. Chem. Front.,2(5),542-547.
MLA 王亚南,et al."Copper-catalyzed stereoselective oxytrifluoro-methylation of propargyl amides for the construction of oxazolines".Org. Chem. Front. 2.5(2015):542-547.
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