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Bronsted acid-catalyzed 1,2-fluorine migration with fluoroepoxides
Alternative Title布朗特酸催化下氟代环氧烷的1,2-氟迁移反应
Luo T(罗涛); Zhang R(张锐); Shen X(沈晓); Zhang W(张伟); Ni CF(倪传法); Hu JB(胡金波)
2015
Source PublicationDalton Trans.
Volume44Issue:45Pages:19636-19641
AbstractA catalytic 1,2-fluorine migration reaction with simple fluoroepoxides at room temperature is reported. Under Bronsted acid catalysis, alpha-fluorinated ketones are efficiently constructed in the absence of an external fluorine source through a 1,2-fluorine migration reaction. The experimental results indicate that the present 1,2-fluorine migration reaction proceeds via a carbocation intermediate.
Subtype论文
Subject Area氟化学
DOI10.1039/c5dt02088c
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000364912100027
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39754
Collection中科院有机氟化学重点实验室
Corresponding AuthorHu JB(胡金波)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Luo T,Zhang R,Shen X,et al. Bronsted acid-catalyzed 1,2-fluorine migration with fluoroepoxides[J]. Dalton Trans.,2015,44(45):19636-19641.
APA 罗涛,张锐,沈晓,张伟,倪传法,&胡金波.(2015).Bronsted acid-catalyzed 1,2-fluorine migration with fluoroepoxides.Dalton Trans.,44(45),19636-19641.
MLA 罗涛,et al."Bronsted acid-catalyzed 1,2-fluorine migration with fluoroepoxides".Dalton Trans. 44.45(2015):19636-19641.
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