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学科主题: 氟化学
题名: Bronsted acid-catalyzed 1,2-fluorine migration with fluoroepoxides
其他题名: 布朗特酸催化下氟代环氧烷的1,2-氟迁移反应
作者: Luo T(罗涛); Zhang R(张锐); Shen X(沈晓); Zhang W(张伟); Ni CF(倪传法); Hu JB(胡金波)
通讯作者: 胡金波
刊名: Dalton Trans.
发表日期: 2015
DOI: 10.1039/c5dt02088c
卷: 44, 期:45, 页:19636-19641
收录类别: SCI
文章类型: 论文
英文摘要: A catalytic 1,2-fluorine migration reaction with simple fluoroepoxides at room temperature is reported. Under Bronsted acid catalysis, alpha-fluorinated ketones are efficiently constructed in the absence of an external fluorine source through a 1,2-fluorine migration reaction. The experimental results indicate that the present 1,2-fluorine migration reaction proceeds via a carbocation intermediate.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000364912100027
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39754
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Luo T,Zhang R,Shen X,et al. Bronsted acid-catalyzed 1,2-fluorine migration with fluoroepoxides[J]. Dalton Trans.,2015,44(45):19636-19641.
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